The aim of the present work is the investigation of polypropylene/graphene oxide nanocamposites. Inthis work, the reinforcing effects of the graphene oxide nanoparticles on the mechanical and thermalproperties of the nonpolar polypropylene are examined. There are two main challenges to improve theproperties of polypropylene by graphene oxide nanoparticles. First, the nanoparticles do not havesuitable dispersion in polymer matrix. Seconde, there is not sufficient adhesion between nanoparticleand polymer chains. In this study, the graphene oxide (GO) surface is modified by a linear alkyl chainvia a bimolecular nucleophilic substitution reaction between the oxygen groups of GO and reactants topromote the homogeneous dispersion of GO in the organic solvent and increase the interfacial adhesionbetween the graphene oxide and polymer matrix. The presence of the alkyl groups on the surface ofgraphene oxide nanoparticles is characterized by FT-IR. To prevent the AGO aggregation in thepolypropylene, the solution-blending method is used to prepare the nanocomposites with 0.1, 0.3, 0.5wt% AGO. The SEM images confirmed the appropriate dispersion of the graphene oxide in thecomposites. The stress-strain analysis, dynamic-mechanical thermal analysis (DMTA), and thermalgravimetric analysis (TGA) are performed to investigate the mechanical and thermal properties ofnanocomposites. The results demonstrated that the Young’s modulus of the polymer is improved by 20, 30 and 34% by the addition of 0.1, 0.3 and 0.5% AGO, respectively. Also, the 10% mass losstemperature for 0.1, 0.3 and 0.5% AGO nanocomposites compared to neat polypropylene increased by2, 8 and 12 C 0, respectively.