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Information Journal Paper

Title

SYNTHESIS OF 4, 10- DINITRO 2, 6, 8, 12- TETRAOXA 4, 10- DIAZAISOWURTZITANE IN THE PRESENCE OF IONIC LIQUIDS

Pages

  41-46

Keywords

4Q2
6Q2
8Q3
10- DIAZAISOWURTZITANE (TEX)Q2
1Q2
3Q3
5Q2
6- TETRAHYDROXYPIPERAZINE (DFTHP)Q2
1-METHYL-3-(4-SULFOBUTYL) IMIDAZOLIUM HYDROGENSULFATEQ3

Abstract

 4, 10- DINITRO 2, 6, 8, 12, tetraoxa 4, 10- diazaisowurtzitane (TEX) is well known as an efficient insensitive high explosive. It is usually prepared via nitration of 1, 4- diformyl- 2, 3, 5, 6- tetrahydroxy piperazine using a mixture of fuming nitric acid and concentrated sulfuric acid. However, these traditional liquid acids are toxic, corrosive and produces hazardous waste. In addition, these acidic mixture cause product decomposition and low yields despite their high catalyst activity. In this research, the use of an efficient catalyst and mild reaction condition for TEX synthesis is reported for the first time. To access the high yield, the amounts of ionic liquid and nitric acid, reaction temperature and reaction time have been studied. The targeted compound (TEX) was characterized by nuclear magnetic resonance spectra (NMR) and Fourier Transform Infrared spectroscopy (FTIR).

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    APA: Copy

    BAYAT, Y., DAMIRCHI, S., & HANIFEZADEH, P.. (2015). SYNTHESIS OF 4, 10- DINITRO 2, 6, 8, 12- TETRAOXA 4, 10- DIAZAISOWURTZITANE IN THE PRESENCE OF IONIC LIQUIDS. JOURNAL OF ENERGETIC MATERIALS, 10(1 (25)), 41-46. SID. https://sid.ir/paper/115387/en

    Vancouver: Copy

    BAYAT Y., DAMIRCHI S., HANIFEZADEH P.. SYNTHESIS OF 4, 10- DINITRO 2, 6, 8, 12- TETRAOXA 4, 10- DIAZAISOWURTZITANE IN THE PRESENCE OF IONIC LIQUIDS. JOURNAL OF ENERGETIC MATERIALS[Internet]. 2015;10(1 (25)):41-46. Available from: https://sid.ir/paper/115387/en

    IEEE: Copy

    Y. BAYAT, S. DAMIRCHI, and P. HANIFEZADEH, “SYNTHESIS OF 4, 10- DINITRO 2, 6, 8, 12- TETRAOXA 4, 10- DIAZAISOWURTZITANE IN THE PRESENCE OF IONIC LIQUIDS,” JOURNAL OF ENERGETIC MATERIALS, vol. 10, no. 1 (25), pp. 41–46, 2015, [Online]. Available: https://sid.ir/paper/115387/en

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