Investigation of the Effect of Boron Promoter on Structural Properties of NiMo Nanocatalyst supported on Red Mud synthesized by Impregnation Method for Hydrocracking and Hydrodesulfurization of Oil Cuts

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Ebrahiminejad Mitra; KARIMZADEH RAMIN

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Journal: FUEL AND COMBUSTION Year:2019 | Volume:12 | Issue:1 Page(s): 97-117

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Title

Investigation of the Effect of Boron Promoter on Structural Properties of NiMo Nanocatalyst supported on Red Mud synthesized by Impregnation Method for Hydrocracking and Hydrodesulfurization of Oil Cuts

Author(s)

Ebrahiminejad Mitra | KARIMZADEH RAMIN | Issue Writer Certificate

Keywords

NiMo nanocatalystQ1

Red MudQ1

BoronQ1

HydrocrackingQ1

HydrodesulfurizationQ1

Abstract

In this paper, NiMo nanocatalysts supported on waste material Red Mud with various amounts of Boron promoter were synthesized via impregnation method and their catalytic activity were tested in Hydrodesulfurization and Hydrocracking processes. The prepared nanocatalysts were characterized using XRD, XRF, FESEM, BET and FTIR analysis. The results obtained by the analysis related to activation Red Mud confirmed that activation process significantly decreases amounts of Ca and Na in the Red Mud and increases its specific surface area. FESEM images comfirmed the formation of nanoparticles with an average particle size of 18. 45 nm. Techniques employed in NiMo/B-ARM nanocatalysts characterization revealed that Boron addition resulted in uniform dispersion of particles on the support surface, an increase in active phase and a decrese in the formation of Ni spineles. Catalytic activity of nanocatalysts in the Hydrocracking process showed that with addition of Boron, liquide products obtained in the process contained higher amounts of kerosene and gasoline and lower amounts of heavy cuts. In addition, hydodesulfurization performance measurments showed that NiMo/B-ARM with 0. 8 wt. % Boron had the best catalytic activity.

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APA: Copy

Ebrahiminejad, Mitra, & KARIMZADEH, RAMIN. (2019). Investigation of the Effect of Boron Promoter on Structural Properties of NiMo Nanocatalyst supported on Red Mud synthesized by Impregnation Method for Hydrocracking and Hydrodesulfurization of Oil Cuts. FUEL AND COMBUSTION, 12(1 ), 97-117. SID. https://sid.ir/paper/138521/en

Vancouver: Copy

Ebrahiminejad Mitra, KARIMZADEH RAMIN. Investigation of the Effect of Boron Promoter on Structural Properties of NiMo Nanocatalyst supported on Red Mud synthesized by Impregnation Method for Hydrocracking and Hydrodesulfurization of Oil Cuts. FUEL AND COMBUSTION[Internet]. 2019;12(1 ):97-117. Available from: https://sid.ir/paper/138521/en

IEEE: Copy

Mitra Ebrahiminejad, and RAMIN KARIMZADEH, “Investigation of the Effect of Boron Promoter on Structural Properties of NiMo Nanocatalyst supported on Red Mud synthesized by Impregnation Method for Hydrocracking and Hydrodesulfurization of Oil Cuts,” FUEL AND COMBUSTION, vol. 12, no. 1 , pp. 97–117, 2019, [Online]. Available: https://sid.ir/paper/138521/en

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