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Information Journal Paper

Title

Melamine-(H2SO4)3/Melamine-(HNO3)3 as an alternative of H2SO4/HNO3: A benign oxidizing system for the oxidation of 1, 4-dihydropyridines reaction under solvent/metal-free conditions

Pages

  47-52

Keywords

Melamine-(H2SO4)3Q1
Melamine-(HNO3)3Q1
1Q2

Abstract

 From the reaction of melamine with sulfuric acid and nitric acid, two Solid Acids Melamine-(H2SO4)3 and Melamine-(HNO3)3 are produced. The mixture of Melamine-(H2SO4)3 and Melamine-(HNO3)3 acts as a powerful system as an alternative of hazardous H2SO4/HNO3 system for the Oxidation of 1, 4-Dihydropyridines under heterogeneous, solvent/metal-free, and mild conditions. In the proposed mechanism, the NO2 + was generated from the mixture of two Solid Acids and this cation performs the Oxidation reaction. This procedure offers advantages such as short reaction times, simple work-up, excellent yields of products without using transition metals and organic solvents. Reagents are cheap, safe, easy-handling, and the synthesis process of them is very simple.

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    APA: Copy

    CHEHARDOLI, G., MOKHLESI, M., & BAGHERI, M.. (2020). Melamine-(H2SO4)3/Melamine-(HNO3)3 as an alternative of H2SO4/HNO3: A benign oxidizing system for the oxidation of 1, 4-dihydropyridines reaction under solvent/metal-free conditions. JOURNAL OF APPLIED RESEARCHES IN CHEMISTRY (JARC), 13(4 ), 47-52. SID. https://sid.ir/paper/180163/en

    Vancouver: Copy

    CHEHARDOLI G., MOKHLESI M., BAGHERI M.. Melamine-(H2SO4)3/Melamine-(HNO3)3 as an alternative of H2SO4/HNO3: A benign oxidizing system for the oxidation of 1, 4-dihydropyridines reaction under solvent/metal-free conditions. JOURNAL OF APPLIED RESEARCHES IN CHEMISTRY (JARC)[Internet]. 2020;13(4 ):47-52. Available from: https://sid.ir/paper/180163/en

    IEEE: Copy

    G. CHEHARDOLI, M. MOKHLESI, and M. BAGHERI, “Melamine-(H2SO4)3/Melamine-(HNO3)3 as an alternative of H2SO4/HNO3: A benign oxidizing system for the oxidation of 1, 4-dihydropyridines reaction under solvent/metal-free conditions,” JOURNAL OF APPLIED RESEARCHES IN CHEMISTRY (JARC), vol. 13, no. 4 , pp. 47–52, 2020, [Online]. Available: https://sid.ir/paper/180163/en

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