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Information Journal Paper

Title

A BRIEF REVIEW OF DIFFERENT INITIATION TECHNIQUES IN ATOM TRANSFER RADICAL POLYMERIZATION

Pages

  13-24

Abstract

 Atom transfer radical polymerization (ATRP) provides a robust route to synthesize well-defined polymers with predetermined molecular weight and low polydispersity index. ATRP as a popular member of controlled radical polymerization (CRP) family provides some advantages over others among which the usage of different initiation techniques are unique features of ATRP. Although Reverse ATRP (RATRP) is an appropriate technique for overcoming oxidation problem, synthesis of block copolymer is impossible by this procedure. Despite RATRP, simultaneous reverse and normal initiation techniques (SR&NI) can be used to synthesize various block copolymers. Activators generated by electron transfer (AGET) and activators regenerated by electron transfer (ARGET) employ environmentally friendly reducing agents to activate a metal complex in its higher oxidation state. However, initiators for continuous activator regeneration (ICAR) initiation techniques use conventional radical initiator. Moreover, ARGET and ICAR ATRP are designed to decrease the metal catalyst concentration to ppm level, which is an important goal to industrial applications.

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  • Cite

    APA: Copy

    KHEZRI, KH., & MAHDAVI, H.. (2014). A BRIEF REVIEW OF DIFFERENT INITIATION TECHNIQUES IN ATOM TRANSFER RADICAL POLYMERIZATION. JOURNAL OF APPLIED RESEARCHES IN CHEMISTRY (JARC), 8(1), 13-24. SID. https://sid.ir/paper/180244/en

    Vancouver: Copy

    KHEZRI KH., MAHDAVI H.. A BRIEF REVIEW OF DIFFERENT INITIATION TECHNIQUES IN ATOM TRANSFER RADICAL POLYMERIZATION. JOURNAL OF APPLIED RESEARCHES IN CHEMISTRY (JARC)[Internet]. 2014;8(1):13-24. Available from: https://sid.ir/paper/180244/en

    IEEE: Copy

    KH. KHEZRI, and H. MAHDAVI, “A BRIEF REVIEW OF DIFFERENT INITIATION TECHNIQUES IN ATOM TRANSFER RADICAL POLYMERIZATION,” JOURNAL OF APPLIED RESEARCHES IN CHEMISTRY (JARC), vol. 8, no. 1, pp. 13–24, 2014, [Online]. Available: https://sid.ir/paper/180244/en

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