HALF-CENTURY JOURNEY FROM SYNTHETIC ORGANIC CHEMISTRY TO MATHEMATICAL STEREOCHEMISTRY THROUGH CHEMOINFORMATICS

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FUJITA SHINSAKU

مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

Journal Paper

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Journal: Iranian Journal of Mathematical Chemistry Year:2016 | Volume:7 | Issue:2 Page(s): 155-221

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Information Journal Paper

Title

HALF-CENTURY JOURNEY FROM SYNTHETIC ORGANIC CHEMISTRY TO MATHEMATICAL STEREOCHEMISTRY THROUGH CHEMOINFORMATICS

Author(s)

FUJITA SHINSAKU | Issue Writer Certificate

Keywords

SPHERICITYQ2

COMBINATORIAL ENUMERATIONQ2

STEREOISOGRAMQ2

STEREOCHEMISTRYQ2

Abstract

My half-century journey started from synthetic organic chemistry. During the first stage of my journey, my interest in STEREOCHEMISTRY was initiated through the investigation on the participation of steric effects in reactive intermediates, cylophanes, strained heterocycles, and organic compounds for photography. In chemoinformatics as the next stage of the journey, I proposed the concept of imaginary transition structures (ITSs) as computer-oriented representation of organic reactions. My interest was stimulated to attack COMBINATORIAL ENUMERATION through the investigation on enumeration of subgraphs of ITSs.Stereochemistry and COMBINATORIAL ENUMERATION was combined in my interest, so that I reached mathematical STEREOCHEMISTRY as the final stage of my journey. Fujita’s unitsubduced-cycle-index (USCI) approach, Fujita’s proligand method, and Fujita’s STEREOISOGRAM approach were developed, so as to integrate van’t Hoff’s way (asymmetry, stereogenicity) and Le Bel’s way (dissymmetry, chirality), which caused continuous confusion in the history of STEREOCHEMISTRY.

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APA: Copy

FUJITA, SHINSAKU. (2016). HALF-CENTURY JOURNEY FROM SYNTHETIC ORGANIC CHEMISTRY TO MATHEMATICAL STEREOCHEMISTRY THROUGH CHEMOINFORMATICS. IRANIAN JOURNAL OF MATHEMATICAL CHEMISTRY, 7(2), 155-221. SID. https://sid.ir/paper/205489/en

Vancouver: Copy

FUJITA SHINSAKU. HALF-CENTURY JOURNEY FROM SYNTHETIC ORGANIC CHEMISTRY TO MATHEMATICAL STEREOCHEMISTRY THROUGH CHEMOINFORMATICS. IRANIAN JOURNAL OF MATHEMATICAL CHEMISTRY[Internet]. 2016;7(2):155-221. Available from: https://sid.ir/paper/205489/en

IEEE: Copy

SHINSAKU FUJITA, “HALF-CENTURY JOURNEY FROM SYNTHETIC ORGANIC CHEMISTRY TO MATHEMATICAL STEREOCHEMISTRY THROUGH CHEMOINFORMATICS,” IRANIAN JOURNAL OF MATHEMATICAL CHEMISTRY, vol. 7, no. 2, pp. 155–221, 2016, [Online]. Available: https://sid.ir/paper/205489/en

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