POLYOXOMOLYBDATE KEGGIN HYBRID INORGANIC-ORGANIC CRYSTAL STRUCTURE HYDROGEN BONDING CYCLIC VOLTAMMETRY

Q: How can I download an article?

To download an article from SID, first log in to the site, search for the article title, and click on the 'Download Article' option.

Q: How can I download an ISI article?

To download an ISI article on SID, enter the keyword or article title in the search bar, view the relevant results, click on the desired article, and select the 'Download Article' option.

Q: How can I access the SID database?

To access the SID database, visit SID.ir, create an account, and log in to access scientific resources.

Q: Is downloading articles from SID free?

Some articles on SID are available for free, while others require payment. Details are specified on the article's page.

Taleghani Somayeh; MIRZAEI MASOUD; ESHTIAGH HOSSEINI HOSSEIN

مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

Journal Paper

Paper Information

Journal: Nashrieh Shimi va Mohandesi Shimi Iran Year:2017 | Volume:36 | Issue:1 Page(s): 117-127

Download Full-Text

Persian Verion

View:

935

Download:

Cites:

Information Journal Paper

Title

POLYOXOMOLYBDATE KEGGIN HYBRID INORGANIC-ORGANIC CRYSTAL STRUCTURE HYDROGEN BONDING CYCLIC VOLTAMMETRY

Author(s)

Taleghani Somayeh | MIRZAEI MASOUD | ESHTIAGH HOSSEINI HOSSEIN | Issue Writer Certificate

Keywords

POLYOXOMOLYBDATEQ1

KEGGINQ1

HYBRID INORGANIC-ORGANICQ1

CRYSTAL STRUCTUREQ2

HYDROGEN BONDINGQ2

CYCLIC VOLTAMMETRYQ1

Abstract

The assembly of phosphomolybdic acid of KEGGIN-type polyoxoanion, [(PO4)Mo12O36]3-, and [La(DMF)8]3+ fragments via layer method under mild condition led to the formation of a new HYBRID INORGANIC-ORGANIC compound with formula [La(DMF)8][(PO4)Mo12O36] (1) (DMF = N,N- dimethylformamide). The hybrid is characterized by using elemental analysis, IR spectroscopy, Energy Dispersive X-ray Spectroscopy analysis (EDS), CYCLIC VOLTAMMETRY, and single crystal X-ray diffraction. This compound crystallizes in the orthorhombic system, space group Pna21 with four molecules per unit cell. The unit cell parameters are: a = 27.1550 (5) A,b =18.5111 (4) A, c = 13.5055 (3) A, and a = b= γ =90o. The final R value was 0.0424 for 65109 observed reflections. The CRYSTAL STRUCTURE is stabilized by non-covalent interactions of type C-H···O, linking the various components into a three-dimensional framework, which results in the formation of a supramolecular structure. Redox activities for the molybdenum centers of 1 have been observed using CYCLIC VOLTAMMETRY.

Cites

No record.

References

Cite

APA: Copy

Taleghani, Somayeh, MIRZAEI, MASOUD, & ESHTIAGH HOSSEINI, HOSSEIN. (2017). POLYOXOMOLYBDATE KEGGIN HYBRID INORGANIC-ORGANIC CRYSTAL STRUCTURE HYDROGEN BONDING CYCLIC VOLTAMMETRY. NASHRIEH SHIMI VA MOHANDESI SHIMI IRAN (PERSIAN), 36(1), 117-127. SID. https://sid.ir/paper/25990/en

Vancouver: Copy

Taleghani Somayeh, MIRZAEI MASOUD, ESHTIAGH HOSSEINI HOSSEIN. POLYOXOMOLYBDATE KEGGIN HYBRID INORGANIC-ORGANIC CRYSTAL STRUCTURE HYDROGEN BONDING CYCLIC VOLTAMMETRY. NASHRIEH SHIMI VA MOHANDESI SHIMI IRAN (PERSIAN)[Internet]. 2017;36(1):117-127. Available from: https://sid.ir/paper/25990/en

IEEE: Copy

Somayeh Taleghani, MASOUD MIRZAEI, and HOSSEIN ESHTIAGH HOSSEINI, “POLYOXOMOLYBDATE KEGGIN HYBRID INORGANIC-ORGANIC CRYSTAL STRUCTURE HYDROGEN BONDING CYCLIC VOLTAMMETRY,” NASHRIEH SHIMI VA MOHANDESI SHIMI IRAN (PERSIAN), vol. 36, no. 1, pp. 117–127, 2017, [Online]. Available: https://sid.ir/paper/25990/en

Related Journal Papers