SULFAMIC ACID CATALYZED RING OPENING OF EPOXIDES WITH AMINES UNDER SOLVENT-FREE CONDITIONS

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HOSSEINI SARVARI M.; SHARGHI H.

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Paper Information

Journal: JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS) Year:2008 | Volume:5 | Issue:3 Page(s): 384-393

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Information Journal Paper

Title

SULFAMIC ACID CATALYZED RING OPENING OF EPOXIDES WITH AMINES UNDER SOLVENT-FREE CONDITIONS

Author(s)

HOSSEINI SARVARI M. | SHARGHI H. | Issue Writer Certificate

Keywords

SULFAMIC ACID

EPOXIDE

AMINES

BETA−AMINO ALCOHOLS

Abstract

SULFAMIC ACID (SA) catalyses the nucleophilic opening of EPOXIDE rings by AMINES leading to the efficient synthesis of b-amino alcohols. The reaction works well with aromatic and aliphatic AMINES in short reaction times and in the absence of solvent. Exclusive trans stereoselectivity is observed for the ring opening of cyclohexene oxide. This method exhibits excellent regioselectivity for preferential nucleophilic attack at the less hindered position during the reaction with unsymmetrical EPOXIDEs.

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APA: Copy

HOSSEINI SARVARI, M., & SHARGHI, H.. (2008). SULFAMIC ACID CATALYZED RING OPENING OF EPOXIDES WITH AMINES UNDER SOLVENT-FREE CONDITIONS. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), 5(3), 384-393. SID. https://sid.ir/paper/282218/en

Vancouver: Copy

HOSSEINI SARVARI M., SHARGHI H.. SULFAMIC ACID CATALYZED RING OPENING OF EPOXIDES WITH AMINES UNDER SOLVENT-FREE CONDITIONS. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS)[Internet]. 2008;5(3):384-393. Available from: https://sid.ir/paper/282218/en

IEEE: Copy

M. HOSSEINI SARVARI, and H. SHARGHI, “SULFAMIC ACID CATALYZED RING OPENING OF EPOXIDES WITH AMINES UNDER SOLVENT-FREE CONDITIONS,” JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), vol. 5, no. 3, pp. 384–393, 2008, [Online]. Available: https://sid.ir/paper/282218/en

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