MN (II), CO (II), NI (II) AND CU (II) COMPLEXES OF A TERTRAAZA MACROCYCLIC LIGAND: SYNTHESIS, CHARACTERIZATION AND BIOLOGICAL SCREENING

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CHANDRA S.; TYAGI M.; SHARMA K.

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Paper Information

Journal: JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS) Year:2009 | Volume:6 | Issue:2 Page(s): 310-316

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Title

MN (II), CO (II), NI (II) AND CU (II) COMPLEXES OF A TERTRAAZA MACROCYCLIC LIGAND: SYNTHESIS, CHARACTERIZATION AND BIOLOGICAL SCREENING

Author(s)

CHANDRA S. | TYAGI M. | SHARMA K. | Issue Writer Certificate

Keywords

MACROCYCLIC LIGAND

METAL COMPLEXES

SPECTRAL CHARACTERIZATION

BIOLOGICAL SCREENING

Abstract

Manganese (II), cobalt (II), nickel (II) and copper (II) complexes with 1,5,11,15-tetraaza-21,22-dioxo-tricyclo [19,3,1,I6,10]- 5,10,15-20-dicosatetraene (L), as a new macrocyclicligand, have been synthesized with and characterized by elemental analysis, molar conductance measurements, magnetic susceptibility measurements, mass, IR, electronic and EPR spectral studies. The molar conductance measurements of the complexes in DMF correspond to non-electrolytic nature of Mn (II), Co (II) and Cu (II) complexes, while showing a 1:2 electrolyte for thew Ni (II) complexe. Thus, these complexes may be formulated as [M(L)X2] and [Ni(L)]X2 (where M=Mn (II), Co (II) and Cu (II) and X=Cl- and NO3-). On the basis of IR, electronic and EPR spectral studies, an octahedral geometry has been assigned for Mn(II) and Co(II), a square planar for Ni(II) and tetragonal for Cu(II) complexes. In vitro ligand and its METAL COMPLEXES were also screened against the growth of some fungal and bacterial species in order to assess their antimicrobial properties.

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APA: Copy

CHANDRA, S., TYAGI, M., & SHARMA, K.. (2009). MN (II), CO (II), NI (II) AND CU (II) COMPLEXES OF A TERTRAAZA MACROCYCLIC LIGAND: SYNTHESIS, CHARACTERIZATION AND BIOLOGICAL SCREENING. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), 6(2), 310-316. SID. https://sid.ir/paper/282308/en

Vancouver: Copy

CHANDRA S., TYAGI M., SHARMA K.. MN (II), CO (II), NI (II) AND CU (II) COMPLEXES OF A TERTRAAZA MACROCYCLIC LIGAND: SYNTHESIS, CHARACTERIZATION AND BIOLOGICAL SCREENING. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS)[Internet]. 2009;6(2):310-316. Available from: https://sid.ir/paper/282308/en

IEEE: Copy

S. CHANDRA, M. TYAGI, and K. SHARMA, “MN (II), CO (II), NI (II) AND CU (II) COMPLEXES OF A TERTRAAZA MACROCYCLIC LIGAND: SYNTHESIS, CHARACTERIZATION AND BIOLOGICAL SCREENING,” JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), vol. 6, no. 2, pp. 310–316, 2009, [Online]. Available: https://sid.ir/paper/282308/en

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