Synthesis, characterization, and electrochemical properties of polyaniline/Co(II) metal-organic framework composites

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ANSARI ASL ZEINAB; Neisi Zeinab; Sedaghat Tahereh; Nobakht Valiollah

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Journal: JOURNAL OF APPLIED CHEMISTRY Year:2019 | Volume:14 | Issue:51 Page(s): 249-263

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Information Journal Paper

Title

Synthesis, characterization, and electrochemical properties of polyaniline/Co(II) metal-organic framework composites

Author(s)

ANSARI ASL ZEINAB | Neisi Zeinab | Sedaghat Tahereh | Nobakht Valiollah | Issue Writer Certificate

Keywords

Metal-organic frameworkQ1

CompositeQ2

Conductive polymerQ1

PolyanilineQ1

Electrochemical propertiesQ1

Abstract

Polyaniline/Co(II) Metal-organic framework Composites (PANI/x%Co-MOF) were synthesized by hydrothermal preparation of Co(II) Metal-organic framework in the presence of as-prepared Polyaniline. The Composites were characterized using powder X-ray diffraction (PXRD), fourier-transform infrared (FT-IR), scanning electron microscopy (SEM), and Co elemental EDS-mapping. Crystal stability of Co(II) Metal-organic framework in the Composites was confirmed by powder X-ray diffraction. The Co elemental EDS-mapping shows that the cobalt is uniformly dispersed in the polymer matrix. Electrochemical properties of prepared Composites were evaluated by cyclic voltammetry (CV) and galvanostatic charge/discharge methods in a conventional three-electrode system. The results of electrochemical studies showed that the PANI/50%Co-MOF Composite has the highest specific capacitance, 144 F g-1, at 1 A g-1 current density in KNO3 (3 M) electrolyte. The Composite electrodes have shown a higher capacity than pure Polyaniline and Co(II) Metal-organic framework, due to the synergistic effects.

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APA: Copy

ANSARI ASL, ZEINAB, Neisi, Zeinab, Sedaghat, Tahereh, & Nobakht, Valiollah. (2019). Synthesis, characterization, and electrochemical properties of polyaniline/Co(II) metal-organic framework composites. JOURNAL OF APPLIED CHEMISTRY, 14(51 ), 249-263. SID. https://sid.ir/paper/381519/en

Vancouver: Copy

ANSARI ASL ZEINAB, Neisi Zeinab, Sedaghat Tahereh, Nobakht Valiollah. Synthesis, characterization, and electrochemical properties of polyaniline/Co(II) metal-organic framework composites. JOURNAL OF APPLIED CHEMISTRY[Internet]. 2019;14(51 ):249-263. Available from: https://sid.ir/paper/381519/en

IEEE: Copy

ZEINAB ANSARI ASL, Zeinab Neisi, Tahereh Sedaghat, and Valiollah Nobakht, “Synthesis, characterization, and electrochemical properties of polyaniline/Co(II) metal-organic framework composites,” JOURNAL OF APPLIED CHEMISTRY, vol. 14, no. 51 , pp. 249–263, 2019, [Online]. Available: https://sid.ir/paper/381519/en

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