Synthesis, characterization and theoretical calculations of some new Cu(II), Co(II), Ni(II) and Cd(II) Schiff base complexes incorporating piperazine head unit

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REZAEIVALA MAJID; BAYAT MEHDI; KEYPOUR HASSAN

مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

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Journal: Applied Chemistry Today Year:2018 | Volume:13 | Issue:46 Page(s): 355-368

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Title

Synthesis, characterization and theoretical calculations of some new Cu(II), Co(II), Ni(II) and Cd(II) Schiff base complexes incorporating piperazine head unit

Author(s)

REZAEIVALA MAJID | BAYAT MEHDI | KEYPOUR HASSAN | Issue Writer Certificate

Keywords

PiperazineQ1

Macroacyclic ligandQ1

Schiff base complexQ1

Theoretical studiesQ1

Abstract

Eight new [NiL1] (1), [CuL1] (2), [CoL1] (3) and [CdL1] (4), [NiL2] (5), [CuL2] (6), [CoL2] (7) and [CdL2] (8) complexes were prepared by the reaction of two new Schiff base ligands and Ni(II), Cu(II), Co(II) and Cd(II) metal ions in equemolar ratios. The ligands, H2L1 and H2L2, were synthesized by reaction of N, N'(2-aminoethyl)(3-aminopropyl)Piperazine and 2-hydroxybenzaldehyde or 2-hydroxy-3-methoxy-benzaldehyde while characterized with IR and 1H, 13C NMR spectroscopy. All complexes have been studied with IR and microanalysis. Theoretical calculations of relevant complexes are done by using one of the hybrid density functional theories which is B3LYP method with GEN keyword.

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APA: Copy

REZAEIVALA, MAJID, BAYAT, MEHDI, & KEYPOUR, HASSAN. (2018). Synthesis, characterization and theoretical calculations of some new Cu(II), Co(II), Ni(II) and Cd(II) Schiff base complexes incorporating piperazine head unit. JOURNAL OF APPLIED CHEMISTRY, 13(46 ), 355-368. SID. https://sid.ir/paper/385988/en

Vancouver: Copy

REZAEIVALA MAJID, BAYAT MEHDI, KEYPOUR HASSAN. Synthesis, characterization and theoretical calculations of some new Cu(II), Co(II), Ni(II) and Cd(II) Schiff base complexes incorporating piperazine head unit. JOURNAL OF APPLIED CHEMISTRY[Internet]. 2018;13(46 ):355-368. Available from: https://sid.ir/paper/385988/en

IEEE: Copy

MAJID REZAEIVALA, MEHDI BAYAT, and HASSAN KEYPOUR, “Synthesis, characterization and theoretical calculations of some new Cu(II), Co(II), Ni(II) and Cd(II) Schiff base complexes incorporating piperazine head unit,” JOURNAL OF APPLIED CHEMISTRY, vol. 13, no. 46 , pp. 355–368, 2018, [Online]. Available: https://sid.ir/paper/385988/en

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