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Information Journal Paper

Title

SYNTHESIS OF COLLAGEN-BASED HYDROGEL NANOCOMPOSITES USING MONTMORILLONITE AND STUDY OF ADSORPTION BEHAVIOR OF CD2+ FROM AQUEOUS SOLUTIONS

Pages

  73-82

Keywords

CD2+ ADSORPTIONQ2

Abstract

 Novel COLLAGEN-based HYDROGEL NANOCOMPOSITEs were synthesized by graft copolymerization of acrylamide and maleic anhydrid in the presence of different amounts of MONTMORILLONITE, using methylenebisacrylamide (MBA) and ammonium persulfate (APS) as crosslinker and initiator, respectively. The optimum amount of clay on the swelling properties of the samples was studied. It was found that the HYDROGEL NANOCOMPOSITEs exhibited improved swelling capacity compared with the clay-free HYDROGEL. Gel content was also studied and the results indicated that the inclusion of MONTMORILLONITE causes an increase in gel content. The sorption behavior of heavy metal ion from aqueous solutions was investigated by its relationship with pH, contact time, initial concentration of metal ion and also, MONTMORILLONITE content of the NANOCOMPOSITEs. The experimental data showed that Cd2+ion adsorption increases with increasing initial concentration of Cd2+ion in solution and the clay content. Also, the results indicated that more than 88% of the maximum adsorption capacities toward Cd2+ion were achieved within the initial 10 minute. Functional groups of the prepared HYDROGELs have shown complexation ability with metal ions and improving HYDROGELs’ adsorption properties. It was concluded that the NANOCOMPOSITEs could be used as fast-responsive, and high capacity sorbent materials in Cd2+ion removing processes. The prepared HYDROGEL NANOCOMPOSITEs were characerized by means of XRD patterns, TGA thermal methods and FTIR spectroscopy. The XRD patterns of NANOCOMPOSITEs showed that the interlayer distance of MONTMORILLONITE was changed and the clay sheets were exfoliated. Furthermore, the results showed that by increasing the MONTMORILLONITE content, thermal stability of the NANOCOMPOSITEs was clearly improved.

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  • Cite

    APA: Copy

    BAGHERI MARANDI, GHOLAM, PEYVAND KERMANI, ZOHREH, & KURDTABAR, MEHRAN. (2013). SYNTHESIS OF COLLAGEN-BASED HYDROGEL NANOCOMPOSITES USING MONTMORILLONITE AND STUDY OF ADSORPTION BEHAVIOR OF CD2+ FROM AQUEOUS SOLUTIONS. IRANIAN JOURNAL OF POLYMER SCIENCE AND TECHNOLOGY (PERSIAN), 26(1 (ISSUE NO. 123)), 73-82. SID. https://sid.ir/paper/389129/en

    Vancouver: Copy

    BAGHERI MARANDI GHOLAM, PEYVAND KERMANI ZOHREH, KURDTABAR MEHRAN. SYNTHESIS OF COLLAGEN-BASED HYDROGEL NANOCOMPOSITES USING MONTMORILLONITE AND STUDY OF ADSORPTION BEHAVIOR OF CD2+ FROM AQUEOUS SOLUTIONS. IRANIAN JOURNAL OF POLYMER SCIENCE AND TECHNOLOGY (PERSIAN)[Internet]. 2013;26(1 (ISSUE NO. 123)):73-82. Available from: https://sid.ir/paper/389129/en

    IEEE: Copy

    GHOLAM BAGHERI MARANDI, ZOHREH PEYVAND KERMANI, and MEHRAN KURDTABAR, “SYNTHESIS OF COLLAGEN-BASED HYDROGEL NANOCOMPOSITES USING MONTMORILLONITE AND STUDY OF ADSORPTION BEHAVIOR OF CD2+ FROM AQUEOUS SOLUTIONS,” IRANIAN JOURNAL OF POLYMER SCIENCE AND TECHNOLOGY (PERSIAN), vol. 26, no. 1 (ISSUE NO. 123), pp. 73–82, 2013, [Online]. Available: https://sid.ir/paper/389129/en

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