Green oxidation of sulfides by dioxide Molybdenum(VI) Schiff base anchored on Fe3O4 nanoparticles in solvent-free condition

Q: How can I download an article?

To download an article from SID, first log in to the site, search for the article title, and click on the 'Download Article' option.

Q: How can I download an ISI article?

To download an ISI article on SID, enter the keyword or article title in the search bar, view the relevant results, click on the desired article, and select the 'Download Article' option.

Q: How can I access the SID database?

To access the SID database, visit SID.ir, create an account, and log in to access scientific resources.

Q: Is downloading articles from SID free?

Some articles on SID are available for free, while others require payment. Details are specified on the article's page.

BEZAATPOUR ABOLFAZL; Bozari Narges; Khatami Sahar

مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

Journal Paper

Paper Information

Journal: Applied Chemistry Today Year:2019 | Volume:14 | Issue:50 Page(s): 55-69

Download Full-Text

Persian Verion

View:

393

Download:

Cites:

Information Journal Paper

Title

Green oxidation of sulfides by dioxide Molybdenum(VI) Schiff base anchored on Fe3O4 nanoparticles in solvent-free condition

Author(s)

BEZAATPOUR ABOLFAZL | Bozari Narges | Khatami Sahar | Issue Writer Certificate

Keywords

Molybdenum (VI)Q1

sulfidesQ1

Schiff baseQ1

Green oxidationQ1

nanocatalystQ1

solvent-freeQ1

Abstract

In this research work, magnetite nanoparticles were prepared, functionalized with molybdenum(VI) salophen complex and characterized using physico-chemical technique. The prepared nanocatalyst was tested for catalytic oxidation of sulfides. The catalytic reaction optimized by changing of solvent, temperature of reaction, time of reaction, [oxidant]/[sulfides] ratio and amount of catalyst. Phenyl methyl sulfide, diphenyl sulfide, dimethyl sulfide, dipropyl sulfide, dibutyl sulfide, Benzyl phenyl sulfide, bis(4-hydroxyphenyl) sulfide, diallyl sulfide and benzothiophene. We obtained the best results in solvent-free condition. The amount of catalyst was optimized by 35% aqueous H2O2 as environmental friendly oxidant. The nanocatalyst is so effective for selective oxidation of thioanisole, dimethyl sulfide, with a >99% conversion, and excellent turnover frequency (131000 h-1<) in shortest time (5 min). The catalyst was easily separated from reaction mixture by using an external magnetic field and reused for several time without significant decreasing in activity.

Cites

No record.

References

No record.

Cite

APA: Copy

BEZAATPOUR, ABOLFAZL, Bozari, Narges, & Khatami, Sahar. (2019). Green oxidation of sulfides by dioxide Molybdenum(VI) Schiff base anchored on Fe3O4 nanoparticles in solvent-free condition. JOURNAL OF APPLIED CHEMISTRY, 14(50 ), 55-69. SID. https://sid.ir/paper/392282/en

Vancouver: Copy

BEZAATPOUR ABOLFAZL, Bozari Narges, Khatami Sahar. Green oxidation of sulfides by dioxide Molybdenum(VI) Schiff base anchored on Fe3O4 nanoparticles in solvent-free condition. JOURNAL OF APPLIED CHEMISTRY[Internet]. 2019;14(50 ):55-69. Available from: https://sid.ir/paper/392282/en

IEEE: Copy

ABOLFAZL BEZAATPOUR, Narges Bozari, and Sahar Khatami, “Green oxidation of sulfides by dioxide Molybdenum(VI) Schiff base anchored on Fe3O4 nanoparticles in solvent-free condition,” JOURNAL OF APPLIED CHEMISTRY, vol. 14, no. 50 , pp. 55–69, 2019, [Online]. Available: https://sid.ir/paper/392282/en

Related Journal Papers