ELECTROCHEMICAL PREPARATION OF A NOVEL ELECTROACTIVE / CONDUCTIVE POLYMER BASED ON B-NAPHTHYLAMINE IN AQUEOUS ACID MEDIA

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BAGHAHI S.M.; BAGHERI A.; MIRAN BEIGI A. A.; TEYMOURI M.

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Journal: Iranian Polymer Journal Year:2002 | Volume:11 | Issue:6 Page(s): 387-401

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Information Journal Paper

Title

ELECTROCHEMICAL PREPARATION OF A NOVEL ELECTROACTIVE / CONDUCTIVE POLYMER BASED ON B-NAPHTHYLAMINE IN AQUEOUS ACID MEDIA

Author(s)

BAGHAHI S.M. | BAGHERI A. | MIRAN BEIGI A. A. | TEYMOURI M. | Issue Writer Certificate

Keywords

CONDUCTIVE POLYMER

Β-NAPHTHYLAMINE

ELECTROCHEMICAL BEHAVIOUR

ELECTROPOLYMERIZATION

AQUEOUS CYCLIC VOLTAMMETRY

Abstract

Electrooxidation of Β-NAPHTHYLAMINE (β-NA) in different aqueous acid media was investigated. The formation of a film adhered to the electrode surface was observed as a principal product and for which a polymer structure through C-N coupling is proposed. A standard three-electrode electrochemical cell was used for voltammetric experiments. In this system, glassy carbon rod, platinum wire, and KCl/saturated Ag/AgCl were used respectively as the working, counter and the reference electrodes. From the analysis of the voltammetric and spectroscopic experiments some aspects of the mechanism of electrooxidation of β-NA leading to the formation of the film was proposed. The effects of various physical and electrochemical parameters such as type of supporting electrolyte, temperature of the cell, pH, concentration of the monomer, scan rate and the number of scan cycles were studied. The electrochemical behavior of the film was reported as a function of these parameters. A quasireversible behaviour was observed from cyclic voltammograms obtained in different acid solutions. The film behaved as a thin-layer cell when it was obtained at low scan rates and dilute solutions of the monomer.

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APA: Copy

BAGHAHI, S.M., BAGHERI, A., MIRAN BEIGI, A. A., & TEYMOURI, M.. (2002). ELECTROCHEMICAL PREPARATION OF A NOVEL ELECTROACTIVE / CONDUCTIVE POLYMER BASED ON B-NAPHTHYLAMINE IN AQUEOUS ACID MEDIA. IRANIAN POLYMER JOURNAL (ENGLISH), 11(6), 387-401. SID. https://sid.ir/paper/529099/en

Vancouver: Copy

BAGHAHI S.M., BAGHERI A., MIRAN BEIGI A. A., TEYMOURI M.. ELECTROCHEMICAL PREPARATION OF A NOVEL ELECTROACTIVE / CONDUCTIVE POLYMER BASED ON B-NAPHTHYLAMINE IN AQUEOUS ACID MEDIA. IRANIAN POLYMER JOURNAL (ENGLISH)[Internet]. 2002;11(6):387-401. Available from: https://sid.ir/paper/529099/en

IEEE: Copy

S.M. BAGHAHI, A. BAGHERI, A. A. MIRAN BEIGI, and M. TEYMOURI, “ELECTROCHEMICAL PREPARATION OF A NOVEL ELECTROACTIVE / CONDUCTIVE POLYMER BASED ON B-NAPHTHYLAMINE IN AQUEOUS ACID MEDIA,” IRANIAN POLYMER JOURNAL (ENGLISH), vol. 11, no. 6, pp. 387–401, 2002, [Online]. Available: https://sid.ir/paper/529099/en

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