EMULSION COPOLYMERIZATION OF METHYL METHACRYLATE AND BUTYL ACRYLATE: THE STUDY OF EFFECTIVE PARAMETERS ON RESIN FORMATION AND ITS PHYSICAL PROPERTIES

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AFGHANI T.; BAGHERI R.; NEHZAT M.S.

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Journal: Iranian Journal of Polymer Science and Technology Year:2006 | Volume:19 | Issue:4 (ISSUE NO. 84) Page(s): 255-264

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Title

EMULSION COPOLYMERIZATION OF METHYL METHACRYLATE AND BUTYL ACRYLATE: THE STUDY OF EFFECTIVE PARAMETERS ON RESIN FORMATION AND ITS PHYSICAL PROPERTIES

Author(s)

AFGHANI T. | BAGHERI R. | NEHZAT M.S. | Issue Writer Certificate

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Abstract

Emulsion copolymerization of methyl methacrylate (MMA) and butyl acrylate (BA) in water was carried out using a basic formula from the raw materials and a semi-batch method in a laboratory scale. Five series of lattices were synthesized by changing ratio of sodium dodecyl sulphate (SDS) to nonyl phenol polyethylene glycol ether (NP-20) in pre-feeding and emulsion solution and also the initiator concentration. All of the syntheses were carried out in the same condition using a constant molar ratio of monomers, water amount and sodium bicarbonate (as a buffer) with the aim of obtaining the highest conversion. The physical properties of the latex samples were also measured. The final conversion of the A 5-2 and A 5-3 samples was above 96% by using molar ratios of SDS to NP-20 in pre-feeding, 1.96 for both samples, and in emulsion solutions, 1.47 and 0.98, respectively and also 4 wt% solution of potassium persulphate for each synthesis. The typical sample, A 5-2 showed 14.5 min drying time, 3.88% absorbed water, the amount of adhesion IB and the cup flow time of 26.3s.

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APA: Copy

AFGHANI, T., BAGHERI, R., & NEHZAT, M.S.. (2006). EMULSION COPOLYMERIZATION OF METHYL METHACRYLATE AND BUTYL ACRYLATE: THE STUDY OF EFFECTIVE PARAMETERS ON RESIN FORMATION AND ITS PHYSICAL PROPERTIES. IRANIAN JOURNAL OF POLYMER SCIENCE AND TECHNOLOGY (PERSIAN), 19(4 (ISSUE NO. 84)), 255-264. SID. https://sid.ir/paper/6756/en

Vancouver: Copy

AFGHANI T., BAGHERI R., NEHZAT M.S.. EMULSION COPOLYMERIZATION OF METHYL METHACRYLATE AND BUTYL ACRYLATE: THE STUDY OF EFFECTIVE PARAMETERS ON RESIN FORMATION AND ITS PHYSICAL PROPERTIES. IRANIAN JOURNAL OF POLYMER SCIENCE AND TECHNOLOGY (PERSIAN)[Internet]. 2006;19(4 (ISSUE NO. 84)):255-264. Available from: https://sid.ir/paper/6756/en

IEEE: Copy

T. AFGHANI, R. BAGHERI, and M.S. NEHZAT, “EMULSION COPOLYMERIZATION OF METHYL METHACRYLATE AND BUTYL ACRYLATE: THE STUDY OF EFFECTIVE PARAMETERS ON RESIN FORMATION AND ITS PHYSICAL PROPERTIES,” IRANIAN JOURNAL OF POLYMER SCIENCE AND TECHNOLOGY (PERSIAN), vol. 19, no. 4 (ISSUE NO. 84), pp. 255–264, 2006, [Online]. Available: https://sid.ir/paper/6756/en

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