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Information Journal Paper

Title

NEW IRON (II) ION- SELECTIVE ELECTRODE BASED ON N- PHENYLAZA-15- CROWN- 5 AS NEUTRAL CARRIER IN PVC MATRIX

Pages

  13-25

Abstract

 Iron, the 26th element in the periodic table, is widely distributed in the earth and arguably one of the most interesting elements. In this research, a PVC MEMBRANE ELECTRODE for Iron (H) ions based on N-PHENYLAZA-15-CROWN-5 as neutral carrier was prepared. The electrode exhibits a Nemstian response for Fe2+ions over a wide concentration range (1.0 x 10-6 to 1.0 x 10-2 mol dm-3) with a slope of 29.2±0.7 mV/ decade. It has a short response time (£15s) and can be used for more than two months without any considerable divergence in the potentials. The results show that this electrode can be used in ethanol/ water and dioxane/ water mixed solvents media until 20% (V/V) and 5% (V/V) volume percent. The complex formation constant between ionophore and iron (II) ions was measured. The SELECTIVITY COEFFICIENTS for iron (II) ions as test species with respect to diverse ions were determined. The electrode was applied to the determination of iron (II) ions in the ferrous sulfate syrup.

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    APA: Copy

    AGHAEI, HOSSEIN, GIAHI, MASOUD, AGHAEI, MEHRAN, & POURNAGHDI, M.. (2006). NEW IRON (II) ION- SELECTIVE ELECTRODE BASED ON N- PHENYLAZA-15- CROWN- 5 AS NEUTRAL CARRIER IN PVC MATRIX. JOURNAL OF SCIENCES (ISLAMIC AZAD UNIVERSITY), 16(60 (CHEMISTRY ISSUE)), 13-25. SID. https://sid.ir/paper/70223/en

    Vancouver: Copy

    AGHAEI HOSSEIN, GIAHI MASOUD, AGHAEI MEHRAN, POURNAGHDI M.. NEW IRON (II) ION- SELECTIVE ELECTRODE BASED ON N- PHENYLAZA-15- CROWN- 5 AS NEUTRAL CARRIER IN PVC MATRIX. JOURNAL OF SCIENCES (ISLAMIC AZAD UNIVERSITY)[Internet]. 2006;16(60 (CHEMISTRY ISSUE)):13-25. Available from: https://sid.ir/paper/70223/en

    IEEE: Copy

    HOSSEIN AGHAEI, MASOUD GIAHI, MEHRAN AGHAEI, and M. POURNAGHDI, “NEW IRON (II) ION- SELECTIVE ELECTRODE BASED ON N- PHENYLAZA-15- CROWN- 5 AS NEUTRAL CARRIER IN PVC MATRIX,” JOURNAL OF SCIENCES (ISLAMIC AZAD UNIVERSITY), vol. 16, no. 60 (CHEMISTRY ISSUE), pp. 13–25, 2006, [Online]. Available: https://sid.ir/paper/70223/en

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