NITRATION OF PHENYLACETYLENE; SYNTHESIS OF β–NITROSTYRENE

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FARHADI MARYAM; TAHERPOUR AVAT (ARMAN)

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Seminar Paper

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Seminar: IRANIAN SEMINAR OF ORGANIC CHEMISTRY
Year:2012 | Issue:19

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Title

NITRATION OF PHENYLACETYLENE; SYNTHESIS OF β–NITROSTYRENE

Author(s)

FARHADI MARYAM | TAHERPOUR AVAT (ARMAN)

Keywords

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Abstract

IN THIS STUDY, THE NITRATION OF PHENYLACETYLENE (H-C≡C-PH) WAS INVESTIGATED. THE INVESTIGATION OF THE PRODUCT HAS SHOWN THAT THE TRIPLE BOND OF THE ACETYLENIC PART OF PHENYLACETYLENE HAS PARTICIPATED IN THE NITRATION PROCESS. IT MEANS THAT IN THE REACTION CONDITION THE ADDITIONAL REACTION ON THE-C≡C- OF PHENYLACETYLENE IS MUCH BETTER THAN THE SUBSTITUTION REACTION ON PH- GROUP. THE STRUCTURES OF THE PRODUCTS WERE ANALYZED BY THE DATA OF IR, 1H-NMR, 13C-NMR AND MS SPECTROSCOPY. THE B3LYP/6-31G* SHOWS THAT THE TRANS-B-NITROSTYRENE IS MORE STABLE THAN ITS CISFORM.THE HOMO LEVEL OF THE TRANS- AND CIS- ISOMERS OF B -NITROSTYRENE ARE -6.95 AND -6.90EV, RESPECTIVELY. THE EXPERIMENTAL AND THEORETICAL ASPECTS OF THIS STUDY WILL BE PRESENTED.

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APA: Copy

FARHADI, MARYAM, & TAHERPOUR, AVAT (ARMAN). (2012). NITRATION OF PHENYLACETYLENE; SYNTHESIS OF β–NITROSTYRENE. IRANIAN SEMINAR OF ORGANIC CHEMISTRY. SID. https://sid.ir/paper/909489/en

Vancouver: Copy

FARHADI MARYAM, TAHERPOUR AVAT (ARMAN). NITRATION OF PHENYLACETYLENE; SYNTHESIS OF β–NITROSTYRENE. 2012. Available from: https://sid.ir/paper/909489/en

IEEE: Copy

MARYAM FARHADI, and AVAT (ARMAN) TAHERPOUR, “NITRATION OF PHENYLACETYLENE; SYNTHESIS OF β–NITROSTYRENE,” presented at the IRANIAN SEMINAR OF ORGANIC CHEMISTRY. 2012, [Online]. Available: https://sid.ir/paper/909489/en

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