IONIC LIQUIDS, AS AN ENVIRONMENTALLY BENIGN SOLVENT AND catalyst, HAVE FOUND MUCH ATTENTION IN VARIOUS FIELDS SUCH AS SYNTHESIS AND CATALYSIS. AMONG THEM, THE HSO3- FUNCTIONALIZED IONIC LIQUIDS HAVE EXHIBITED GREAT POTENTIAL IN REPLACEMENT OF CONVENTIONAL HOMOGENEOUS AND HETEROGENEOUS ACIDIC CATALYSIS [1]. FORMAMIDINES ARE DERIVATIVES OF THE UNSTABLE IMIDIC ACID HAVING A UNIQUE AND FASCINATING SPECTRUM OF BIOLOGICAL AND PHARMACOLOGICAL ACTIVITY [2]. IN THIS RESEARCH, TWO H-IMAILS; (PROPYL-3-SULFONIC) IMIDAZOLIUM TRIFLUOROMETHANE SULFONATE, [IMPS][TFO], AND (BUTYL-4-SOLFONIC) IMIDAZOLIUM TRIFLUOROMETHANE SULFONATE, [IMBS][TFO], WERE PREPARED AND CHARACTERIZED. THE BRONSTED ACIDITY OF THEM WAS DETERMINED BY HAMMETT METHOD WITH UV/VIS SPECTROSCOPY. THE APPLICABILITY OF THESE AILS AS NOVEL catalystS WAS EXAMINED IN THE SYNTHESIS OF Symmetric AND ASymmetric FORMAMIDINES BY CONDENSING SUBSTITUTED ANILINES WITH METHYL OR ETHYL ORTHOFORMATES AND N,N-DIMETHYLFORMAMIDINE DIMETHYL ACETAL (DMF-DMA) IN WATER AT 35OC. THIS METHOD IS IMPORTANT FROM BOTH ENVIRONMENTAL POINT OF VIEW AND ECONOMIC CONSIDERATIONS; BECAUSE IT PRODUCES LITTLE WASTE, GOOD YIELD, SHORT REACTION TIME, SIMPLE WORK-UP, catalyst RECOVERY AND ALSO REUSABILITY. THE catalystS ARE RECYCLABLE AND COULD BE REUSED FOR AT LEAST SEVEN TIMES WITHOUT SIGNIFICANT LOSS OF THEIR ACTIVITY.