Among the six classes of pro-2-groups of finite and fixed co-classes and trivial Schur Multiplicator which studied by Abdolzadeh and Eick in 2009, there are two classesS5=<a, b ½ [b, a2] =1, a2= [b, a] 2, (b2) [b, a] b2=1>andS6=<a, t, b ½ a2=b2, [b, a]2=1, ta=t-1 [b, a], bt=aba>that have been conjectured to have deficiency zero presentations. In this paper we prove these conjectures. This completes the efficiency of all six classes of pro-2-groups of fixed co-classes.