Let $G=(V, E)$ be a simple graph. A function $f: V\rightarrow \mathbb{N}\cup \{0\}$ is called a configuration of pebbles on the vertices of $G$ and the quantity $\vert f\vert=\sum_{u\in V}f(u)$ is called the weight of $f$ which is just the total number of pebbles assigned to vertices. A pebbling step from a vertex $u$ to one of its neighbors $v$ reduces $f(u)$ by two and increases $f(v)$ by one. A pebbling configuration $f$ is said to be solvable if for every vertex $ v $, there exists a sequence (possibly empty) of pebbling moves that results in a pebble on $v$. The pebbling number $ \pi(G) $ equals the minimum number $ k $ such that every pebbling configuration $ f $ with $ \vert f\vert = k $ is solvable. Let $ G $ be a connected graph constructed from pairwise disjoint connected graphs $ G_1, . . ., G_k $ by selecting a vertex of $ G_1 $, a vertex of $ G_2 $, and identifying these two vertices. Then continue in this manner inductively. We say that $ G $ is a polymer graph, obtained by point-attaching from monomer units $ G_1, . . ., G_k $. In this paper, we study the pebbling number of some polymers.