The development of an optical pH sensor based on immobilization of quinizarin (1,4-dihydroxyanthraquinone) on a triacetylcellulose membrane was described. The resulting membrane exhibited fast color change from yellow to violet, while changing the pH in alkaline region. The immobilized quinizarin showed a broader dynamic range from (pH 9.4-11.4) with respect to free form (pH 8.8-10.4). The sensor response was fully reversible and fast (<20 s) under the batch conditions with pH between 7 and 12.5. The sensor showed excellent long term stability (more than three months) and high reproducibility (R.S.D. less than 2%). The Ka values for free and immobilized dye were evaluated and the chemical reactivity of the quinizarin in solution and after immobilization was also described.

The protection of transmission and sub-transmission lines is conducted by overcurrent, line differential and distance protections among which the use of distance protection is very common.Mal-operation of protection equipment, including distance protection, can occur due to improper choose of the setting. This paper presents the proper method for calculation of the phase-to-phase loop resistance reach of distance protection with Quad characteristic and the impedance starter at the sub-transmission level to prevent mal-operation of the distance relay when processing its algorithm. In this work, based on the practical experiences on several industrial distance relays, it is shown that there is a possibility of improper detection of the fault loop by distance protection and then improper relay operation for out of zone faults. After review of the subject, and expressing the mathematical relations governing the problem, the appropriate phase-to-phase loop resistance reach determination method is put forward. Finally, using the information obtained from a practical incident, the efficiency of the proposed method is verified.