With the rapid increase in the use of search engines, the need for developing more effective information retrieval and ranking methods has become critical. One of the key challenges in information retrieval is predicting Query performance, which involves estimating how well a search engine can fulfill a user's information need. Accurate prediction of Query performance allows search engines to take adaptive actions, such as Query reformulation or ranking adjustment, to enhance retrieval effectiveness. Query Performance Prediction (QPP) methods fall into two main categories: pre-retrieval prediction and post-retrieval prediction. Pre-retrieval predictors estimate Query difficulty before the retrieval process, relying on linguistic and statistical Query features rather than retrieved documents. In contrast, post-retrieval prediction methods assess Query performance based on the ranking list and document collection, providing deeper insights into retrieval effectiveness. In this study, we propose a novel unsupervised post-retrieval QPP method that evaluates Query performance by analyzing the clustering behavior of retrieved documents. Our method defines five new metrics—CC, DCIC, DCNIC, DCNICR, and CCR— to measure the distribution and coherence of retrieved documents. These metrics help assess Query difficulty by capturing how documents group into clusters, identifying outlier documents that do not fit well into clusters, and evaluating the overall structure of retrieved results. By leveraging these metrics, our approach provides a more fine-grained estimation of Query performance without requiring human-labeled data. To evaluate the effectiveness of the proposed method, we conduct experiments on three datasets: TREC DL 2019, TREC DL 2020, and DL-Hard. The results demonstrate that our approach improves Spearman's correlation coefficient by 0.009 and 0.163 on the TREC DL 2019 and DL-Hard datasets, respectively. Additionally, it increases Pearson’s correlation coefficient by 0.037 on the TREC DL 2020 dataset compared to state-of-the-art unsupervised QPP methods. These improvements indicate that clustering-based QPP methods can effectively capture Query difficulty and retrieval quality without the need for external supervision.