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Journal: 

PETROLEUM RESEARCH

Issue Info: 
  • Year: 

    2012
  • Volume: 

    21
  • Issue: 

    68
  • Pages: 

    44-53
Measures: 
  • Citations: 

    0
  • Views: 

    1224
  • Downloads: 

    0
Abstract: 

Effects of template type on the catalytic performance of SAPO-34 catalyst in conversion of methanol to light olefins (MTO) have been investigated. SAPO34 molecular sieves were synthesized by hydrothermal method, using morpholine tetraethyl ammonium hydroxide and dipropylamine as the template in the synthesis of gel with molar composition of Al2O3: P2O5: SiO2: template: H2O being 1:1:0.6:2:50, respectively. The produced samples were characterized by XRD, SEM, NH3-TPD and TGA-DTA techniques. These results showed that template type affects crystal size, morphology, crystallinity and purity of samples. It was found that the average SAPO-34 crystal size increased when morpholine was used as the template. Conversion of methanol to light olefins using acidic SAPO34 as the reaction catalyst was studied in a fixed bed reactor in the temperature range of 250–450oC, atmospheric pressure and WHSV=1 hr-1. Although all the catalysts showed similar activity and product distribution, the catalyst obtained using morpholine as the template, had the shortest lifetime.

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Issue Info: 
  • Year: 

    2014
  • Volume: 

    8
Measures: 
  • Views: 

    157
  • Downloads: 

    61
Abstract: 

ADSORPTION EQUILIBRIUM OF CH4 AND CO2 ON SILICOALUMINA-PHOSPHATE MOLECULAR SIEVE (SAPO-34) HAS BEEN STUDIED IN VARIOUS OPERATING CONDITIONS, EXPERIMENTALLY AND THEORETICALLY. THE EXPERIMENTS WERE PERFORMED IN THE BATCH SYSTEM ON THE BASE OF VOLUMETRIC MEASUREMENT TECHNIQUE FOR THE ABSOLUTE GAS PRESSURE RANGE OF 1 TO 10 BAR AND THREE DIFFERENT TEMPERATURES OF 303, 313 AND 323 K. THE MAXIMUM ADSORPTION CAPACITIES OF CH4 AND CO2 WERE DETERMINED AS 1.254 AND 5.125 MMOL/GR, RESPECTIVELY, AT THE EQUILIBRIUM PRESSURE OF 9.0 BAR AND TEMPERATURE OF 303 K. THE EXPERIMENTAL ISOTHERMS WERE MODELED ON THE BASE OF DIFFERENT ISOTHERM EQUATIONS; LANGMUIR, SIPS, TOTH AND UNILAN BY MINIMIZING THE MEAN RELATIVE DIFFERENCE BETWEEN THE MODEL AND EXPERIMENTAL ADSORPTION CAPACITY. AMONG THE SO-CALLED MODELS, LANGMUIR HAS SHOWN THE BEST AGREEMENT WITH THE EXPERIMENTAL RESULTS, AND IT REVEALS THAT THE ADSORPTION MECHANISM WOULD BE MONOLAYER ADSORPTION WITH THE HOMOGENEOUS ADSORPTION SYSTEM OF CH4-SAPO34 AND CO2-SAPO34.

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