Groundwater quality assessment and selection of appropriate methods of zoning depends on the region conditions, and the data availability. The correct choice of interpolation is a key milestone and a major step forward in the management of groundwater resources. The aim of this study was to evaluate the quality of groundwater for drinking and irrigation purposes in the west of Marivan city, Iran. For this purpose, data from 1985 to 2011, and the parameters of salinity, chlorine, concentration of dissolved substances, sulfate, water hardness, sodium, sodium adsorption ratio were used. Analysis of variance (ANOVA) and the LDS test was used to compare treatments and the differences between various stations respectively. For determining the most appropriate location and zoning methods for the above parameters, geographical information system (GIS) was used. For this purpose, a geostatistics method of simple Kriging, and deterministic techniques such as inverse distance weighting, radial basis function, local estimator and general estimators were applied to annual and seasonal data. The results showed that the quality of water in the area is appropriate and acceptable for drinking. Also for the irrigation, most of the study area is located within an acceptable range. Different criteria such as the root mean squared error (RMSE), mean absolute error (MAE) and coefficient of determination (R2) were used to evaluate spatial interpolation results. Based on these criteria, among the different methods of interpolation techniques, the local estimator for estimating the parameters of sulfate, soluble solids concentration and salinity, the radial basis function for estimating parameters of sodium and sodium absorption ratio, and the general estimator method for chlorine at annual scale were the most appropriate methods.