The water transfer behavior of cation exchange selemion CMV and anion exchange
selemion AMV and DMV membranes (Asahi Glass Co., Japan), has been studied in the
vanadium redox cell, as was the water transfer across cation exchange Nafion 117 membrane
(E.I. Du Pont, U.S.A.) and a composite membrane which was prepared by crosslinking Daramic
(a microporous separator, W.R. Grace, USA) with divinylbenzene (DVB) followed by
sulfonation [1,2]. The earlier water transport studies of a variety of commercial ion exchange
membranes and non-ionic separators in the vanadium redox cell have shown that the net water
transport through anion exchange membranes and non-ionic separators in the vanadium redox
cell is from the positive half cell (+ve) to the negative half cell (-ve), while for cation exchange
membranes, the net water transport is in the opposite direction. It was found that for cation
exchange membranes, the hydrogen ion concentration gradient causes the osmotic water
transfer rather than the vanadium ions which make only a minor contribution, while for anion
exchange membranes, the sulphate ion concentration gradient is responsible for the osmotic
pressure effect.