OPTIMIZATION OF MICRO KINETICS PARAMETERS OF OXIDATIVE DESULFURIZATION PROCESSES OF 4,6-DIMETHYL DIBENZOTHIOPHENE WITH ULTRASOUND WAVES AND WITHOUT ULTRASOUND WAVES FROM MODEL DIESEL

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ABDOOS NAVID; AKBARI AZAM; OMIDKHAH MOHAMMAD REZA; TOWFIGHI DARIAN JAFAR

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Journal: PETROLEUM RESEARCH Year:2016 | Volume:26 | Issue:87-2 Page(s): 52-63

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Title

OPTIMIZATION OF MICRO KINETICS PARAMETERS OF OXIDATIVE DESULFURIZATION PROCESSES OF 4,6-DIMETHYL DIBENZOTHIOPHENE WITH ULTRASOUND WAVES AND WITHOUT ULTRASOUND WAVES FROM MODEL DIESEL

Author(s)

ABDOOS NAVID | AKBARI AZAM | OMIDKHAH MOHAMMAD REZA | TOWFIGHI DARIAN JAFAR | Issue Writer Certificate

Keywords

OXIDATIVE DESULFURIZATIONQ1

ULTRASOUNDQ1

LNGMUIR HINSHELWOODQ1

ELEY RIDEALQ1

GENETIC ALGORITHMQ2

Abstract

According to the benefits of OXIDATIVE DESULFURIZATION (ODS) and ULTRASOUND assisted OXIDATIVE DESULFURIZATION (UAOD) processes and in order to industrialize these processes, it is necessary that the kinetics of these processes be studied and modeled, so as to be able to design and simulate them in semi industrial and industrial scale. Therefore, kinetics modeling of OXIDATIVE DESULFURIZATION reaction of 4, 6-DMDBT over molybdenum catalyst supported on alumina has been investigated. For expression of reaction kinetics equations, Langmuir Hinshelwood and ELEY RIDEAL mechanisms have been used. GENETIC ALGORITHM was used for optimization. Based on, Langmuir-Hinshelwood and ELEY RIDEAL models results, Langmuir-Hinshelwood mechanism can describe the kinetic behavior of UAOD and ODS processes. Micro kinetics equations and rate determining step are identified according to the results of the models.

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APA: Copy

ABDOOS, NAVID, AKBARI, AZAM, OMIDKHAH, MOHAMMAD REZA, & TOWFIGHI DARIAN, JAFAR. (2016). OPTIMIZATION OF MICRO KINETICS PARAMETERS OF OXIDATIVE DESULFURIZATION PROCESSES OF 4,6-DIMETHYL DIBENZOTHIOPHENE WITH ULTRASOUND WAVES AND WITHOUT ULTRASOUND WAVES FROM MODEL DIESEL. PETROLEUM RESEARCH, 26(87-2), 52-63. SID. https://sid.ir/paper/114824/en

Vancouver: Copy

ABDOOS NAVID, AKBARI AZAM, OMIDKHAH MOHAMMAD REZA, TOWFIGHI DARIAN JAFAR. OPTIMIZATION OF MICRO KINETICS PARAMETERS OF OXIDATIVE DESULFURIZATION PROCESSES OF 4,6-DIMETHYL DIBENZOTHIOPHENE WITH ULTRASOUND WAVES AND WITHOUT ULTRASOUND WAVES FROM MODEL DIESEL. PETROLEUM RESEARCH[Internet]. 2016;26(87-2):52-63. Available from: https://sid.ir/paper/114824/en

IEEE: Copy

NAVID ABDOOS, AZAM AKBARI, MOHAMMAD REZA OMIDKHAH, and JAFAR TOWFIGHI DARIAN, “OPTIMIZATION OF MICRO KINETICS PARAMETERS OF OXIDATIVE DESULFURIZATION PROCESSES OF 4,6-DIMETHYL DIBENZOTHIOPHENE WITH ULTRASOUND WAVES AND WITHOUT ULTRASOUND WAVES FROM MODEL DIESEL,” PETROLEUM RESEARCH, vol. 26, no. 87-2, pp. 52–63, 2016, [Online]. Available: https://sid.ir/paper/114824/en

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