Hydrothermal Synthesis of Zn-ZSM5 Catalyst for xylene isomerizationHydrothermal Synthesis of Zn-ZSM5 Catalyst for xylene isomerization

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Rasouli Milad; Yaghobi Nakisa; ATASHI HOSSEIN; MOHEBBI KALHORI DAVOD

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Journal: PETROLEUM RESEARCH Year:2018 | Volume:28 | Issue:101 Page(s): 101-111

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Title

Hydrothermal Synthesis of Zn-ZSM5 Catalyst for xylene isomerizationHydrothermal Synthesis of Zn-ZSM5 Catalyst for xylene isomerization

Author(s)

Rasouli Milad | Yaghobi Nakisa | ATASHI HOSSEIN | MOHEBBI KALHORI DAVOD | Issue Writer Certificate

Keywords

ZSM5Q1

IsomerizationQ1

Para-xyleneQ1

Xylene LossQ1

Catalyst StabilityQ1

Abstract

The addition of Zinc to the synthesis of ZSM-5 catalysts (Si/Al=21) was studied in xylene Isomerization reactions. Physicochemical characteristics of the prepared catalysts were evaluated by XRD, BET, SEM, FTIR, NH3-TPD and TG analyses. Zn incorporation strongly increased the strong acid (Brø nsted) sites and reduced the weak acidity (Lewis). Higher strong acidity led to higher PX yield and Lower weak acidity led to lower coke formation and more catalytic stability. (0. 5 wt. %)Zn-ZSM-5 as an efficient and stable catalyst for xylene Isomerization reactions demonstrated high PX yield (18. 5 wt. %), high EB conversion (43. 6%) and low Xylene Loss (3. 3 %).

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APA: Copy

Rasouli, Milad, Yaghobi, Nakisa, ATASHI, HOSSEIN, & MOHEBBI KALHORI, DAVOD. (2018). Hydrothermal Synthesis of Zn-ZSM5 Catalyst for xylene isomerizationHydrothermal Synthesis of Zn-ZSM5 Catalyst for xylene isomerization. PETROLEUM RESEARCH, 28(101 ), 101-111. SID. https://sid.ir/paper/114919/en

Vancouver: Copy

Rasouli Milad, Yaghobi Nakisa, ATASHI HOSSEIN, MOHEBBI KALHORI DAVOD. Hydrothermal Synthesis of Zn-ZSM5 Catalyst for xylene isomerizationHydrothermal Synthesis of Zn-ZSM5 Catalyst for xylene isomerization. PETROLEUM RESEARCH[Internet]. 2018;28(101 ):101-111. Available from: https://sid.ir/paper/114919/en

IEEE: Copy

Milad Rasouli, Nakisa Yaghobi, HOSSEIN ATASHI, and DAVOD MOHEBBI KALHORI, “Hydrothermal Synthesis of Zn-ZSM5 Catalyst for xylene isomerizationHydrothermal Synthesis of Zn-ZSM5 Catalyst for xylene isomerization,” PETROLEUM RESEARCH, vol. 28, no. 101 , pp. 101–111, 2018, [Online]. Available: https://sid.ir/paper/114919/en

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