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Information Journal Paper

Title

SIMULTANEOUS DETERMINATION OF MAGNESIUM AND STRONTIUM IN SOLID-BASE PROPELLANTS BY FIRST-DERIVATIVE SPECTROPHOTOMETRY IN MICELLAR MEDIA

Pages

  3-10

Abstract

 A simple and sensitive derivative spectrophotometric method was proposed for the simultaneous determination of MAGNESIUM and STRONTIUM in mixture. The method was based on the color reaction of MAGNESIUM and STRONTIUM with 1, 8-dihydroxy anthrone as a new chromogenic reagent in cationic surfactant cetylpyridinium chloride (CPC) micellar media. The chemical variables affecting the maximum sensitivity of both ions (e.g. pH, reagent and surfactant concentrations, temperature and instrumental parameters) were evaluated and optimized. Under the optimum experimental conditions, calibration graph was linear in the range of 0.05-1.80 and 0.10-1.60 of MAGNESIUM and STRONTIUM at 515 and 565 nm (the zero crossing point of Mg and Sr complexes in the first order derivative mode) respectively. The reproducibility for 5 replicate determinations at 0.5 mg Ml-1 of Mg(II) and Sr(II) were 0.98% and 1.34% respectively. The interference effect of some cations and anions was also studied and elevated using appropriate masking agents. The proposed method was successfully applied for the simultaneous determination of these ions in SOLID-BASE PROPELLANTs and the obvious data were compared with ICP-AES results.

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  • Cite

    APA: Copy

    BABAEI, SAEID, & EGHDAMTALAB, M.. (2009). SIMULTANEOUS DETERMINATION OF MAGNESIUM AND STRONTIUM IN SOLID-BASE PROPELLANTS BY FIRST-DERIVATIVE SPECTROPHOTOMETRY IN MICELLAR MEDIA. JOURNAL OF ENERGETIC MATERIALS, 3(2), 3-10. SID. https://sid.ir/paper/115415/en

    Vancouver: Copy

    BABAEI SAEID, EGHDAMTALAB M.. SIMULTANEOUS DETERMINATION OF MAGNESIUM AND STRONTIUM IN SOLID-BASE PROPELLANTS BY FIRST-DERIVATIVE SPECTROPHOTOMETRY IN MICELLAR MEDIA. JOURNAL OF ENERGETIC MATERIALS[Internet]. 2009;3(2):3-10. Available from: https://sid.ir/paper/115415/en

    IEEE: Copy

    SAEID BABAEI, and M. EGHDAMTALAB, “SIMULTANEOUS DETERMINATION OF MAGNESIUM AND STRONTIUM IN SOLID-BASE PROPELLANTS BY FIRST-DERIVATIVE SPECTROPHOTOMETRY IN MICELLAR MEDIA,” JOURNAL OF ENERGETIC MATERIALS, vol. 3, no. 2, pp. 3–10, 2009, [Online]. Available: https://sid.ir/paper/115415/en

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