STUDIES OF THE THERMAL DECOMPOSITION, NON-ISOTHERMAL KINETIC AND THERMODYNAMIC PROPERTIES OF AMINE SALT OF 3-NITRO-1, 2, 4-TRIAZOL-5-ONE (NTO)

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NAJAFI M.; KALANTARI SAMANGANI A.

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Journal: JOURNAL OF ENERGETIC MATERIALS Year:2011 | Volume:6 | Issue:1 (11) Page(s): 3-11

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Title

STUDIES OF THE THERMAL DECOMPOSITION, NON-ISOTHERMAL KINETIC AND THERMODYNAMIC PROPERTIES OF AMINE SALT OF 3-NITRO-1, 2, 4-TRIAZOL-5-ONE (NTO)

Author(s)

NAJAFI M. | KALANTARI SAMANGANI A. | Issue Writer Certificate

Keywords

3-NITRO-1Q2

2Q3

4-TRIAZOLE-5-ONE (NTO)Q3

AMINE SALTSQ3

THERMAL DECOMPOSITIONQ3

NON-ISOTHERMAL KINETICSQ3

Abstract

The salts of 3-NITRO-1, 2, 4-triazol-5-one (NTO) have received much attention in recent years due to their great application as energetic ballistic modifiers for solid propellants and gun propellant formulations. In this work, thermal behavior of four new AMINE SALTS of NTO among dimethyleguanidine, diethyleguanidine cyclohexamethylenetetramine and semicarbazide were studied under a non-isothermal condition by DSC and TG-DTG methods. The kinetic parameters (Arheniuse) were obtained from analysis of the DSC and TG curves by the Agrawal, Satava-Sestak and Ordinary-integral methods and the enthalpies of decomposition of the AMINE SALTS of NTO were calculated. The results in terms of activation energy showed that AMINE SALTS of NTO are thermally more unstable than NTO and show different THERMAL DECOMPOSITION mechanisme.

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APA: Copy

NAJAFI, M., & KALANTARI SAMANGANI, A.. (2011). STUDIES OF THE THERMAL DECOMPOSITION, NON-ISOTHERMAL KINETIC AND THERMODYNAMIC PROPERTIES OF AMINE SALT OF 3-NITRO-1, 2, 4-TRIAZOL-5-ONE (NTO). JOURNAL OF ENERGETIC MATERIALS, 6(1 (11)), 3-11. SID. https://sid.ir/paper/115428/en

Vancouver: Copy

NAJAFI M., KALANTARI SAMANGANI A.. STUDIES OF THE THERMAL DECOMPOSITION, NON-ISOTHERMAL KINETIC AND THERMODYNAMIC PROPERTIES OF AMINE SALT OF 3-NITRO-1, 2, 4-TRIAZOL-5-ONE (NTO). JOURNAL OF ENERGETIC MATERIALS[Internet]. 2011;6(1 (11)):3-11. Available from: https://sid.ir/paper/115428/en

IEEE: Copy

M. NAJAFI, and A. KALANTARI SAMANGANI, “STUDIES OF THE THERMAL DECOMPOSITION, NON-ISOTHERMAL KINETIC AND THERMODYNAMIC PROPERTIES OF AMINE SALT OF 3-NITRO-1, 2, 4-TRIAZOL-5-ONE (NTO),” JOURNAL OF ENERGETIC MATERIALS, vol. 6, no. 1 (11), pp. 3–11, 2011, [Online]. Available: https://sid.ir/paper/115428/en

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