MECHANISM OF REDUCTION OF COPPER CHLORIDE FROM LIQUID N-BUTYLAMINE- NAPHTHALENE ELECTROLYTE

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SADR NEJAD S.KH.; BORNUSH A.; GHORBANI M.

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Journal: Year:2001 | Volume:35 | Issue:3 (73) Page(s): 337-348

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Title

MECHANISM OF REDUCTION OF COPPER CHLORIDE FROM LIQUID N-BUTYLAMINE- NAPHTHALENE ELECTROLYTE

Author(s)

SADR NEJAD S.KH. | BORNUSH A. | GHORBANI M. | Issue Writer Certificate

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Abstract

Aromatic solutions containing N-Butylamine salts have sufficient thermo-chemical stability, wide polarization potential, high boiling point and acceptable dielectric coefficient suitable for electrolytic coating of the active metallic ions. In this study, nucleation/growth kinetics of thin metallic layers precipitated from copper containing N-Butylamine complexes dissolved in naphthalene is investigated via cyclic voltammetry, chronoamperometry and electrochemical impedance frequency response method. Results indicate –an instantaneous three-dimensional electrochemical crystallization of copper concomitant with a diffusion-controlled growth regime. The diffusion coefficient of copper containing complex and the standard rate constant of the reaction are calculated from the data, which appear to be in the range of 3-6 x 10-6 cm2/s and 2-6 x 10-3 cm/s., respectively. The relatively small reaction as well as diffusion rates seem to be due to the complexion of copper ions with large aromatic legends.

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APA: Copy

SADR NEJAD, S.KH., BORNUSH, A., & GHORBANI, M.. (2001). MECHANISM OF REDUCTION OF COPPER CHLORIDE FROM LIQUID N-BUTYLAMINE- NAPHTHALENE ELECTROLYTE. JOURNAL OF FACULTY OF ENGINEERING (UNIVERSITY OF TEHRAN), 35(3 (73)), 337-348. SID. https://sid.ir/paper/14073/en

Vancouver: Copy

SADR NEJAD S.KH., BORNUSH A., GHORBANI M.. MECHANISM OF REDUCTION OF COPPER CHLORIDE FROM LIQUID N-BUTYLAMINE- NAPHTHALENE ELECTROLYTE. JOURNAL OF FACULTY OF ENGINEERING (UNIVERSITY OF TEHRAN)[Internet]. 2001;35(3 (73)):337-348. Available from: https://sid.ir/paper/14073/en

IEEE: Copy

S.KH. SADR NEJAD, A. BORNUSH, and M. GHORBANI, “MECHANISM OF REDUCTION OF COPPER CHLORIDE FROM LIQUID N-BUTYLAMINE- NAPHTHALENE ELECTROLYTE,” JOURNAL OF FACULTY OF ENGINEERING (UNIVERSITY OF TEHRAN), vol. 35, no. 3 (73), pp. 337–348, 2001, [Online]. Available: https://sid.ir/paper/14073/en

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