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Information Journal Paper

Title

Cu decorated multiwalled carbon nanotubes: Application to electrocatalytic oxidation and determination of 4-nitrophenol in river water samples by square-wave voltammetry

Pages

  51-60

Abstract

 A simple and fast electrochemical method was described and evaluated for the determination of hazardous compound, 4-Nitrophenol. In this work, trace amounts of 4-Nitrophenol were determined by square – wave voltammetry. A glassy carbon electrode was modified with Multi-walled carbon nanotubes and Copper nanoparticles. A synergistic effect was observed between Cu nanoparticles and carbon nanotubes which resulted in enhanced oxidation peak current of 4-Nitrophenol. The modified electrode showed more sensitivity towards 4-Nitrophenol compared to unmodified one. A wide linear concentration range from 0. 2 to 298. 0 μ M was obtained for 4-Nitrophenol with a detection limit of 0. 06 μ M. Reproducibility and repeatability of the method were evaluated for determination of 4-Nitrophenol (0. 1 mM) as 3. 47% and 2. 30%, respectively (relative standard deviation, RSD %), which are acceptable. The method was applied to the analysis of 4-Nitrophenol (22. 2 μ M) in spiked River water samples, successfully. Simplicity, sensitivity, selectivity and high efficiency of the proposed method can be used in routine analysis of trace amounts of 4-Nitrophenol in polluted waters.

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  • Cite

    APA: Copy

    JALALI, FAHIMEH, Taher, Ali, & Hasanvand, Zahra. (2018). Cu decorated multiwalled carbon nanotubes: Application to electrocatalytic oxidation and determination of 4-nitrophenol in river water samples by square-wave voltammetry. ADVANCES IN ENVIRONMENTAL TECHNOLOGY, 4(1), 51-60. SID. https://sid.ir/paper/348555/en

    Vancouver: Copy

    JALALI FAHIMEH, Taher Ali, Hasanvand Zahra. Cu decorated multiwalled carbon nanotubes: Application to electrocatalytic oxidation and determination of 4-nitrophenol in river water samples by square-wave voltammetry. ADVANCES IN ENVIRONMENTAL TECHNOLOGY[Internet]. 2018;4(1):51-60. Available from: https://sid.ir/paper/348555/en

    IEEE: Copy

    FAHIMEH JALALI, Ali Taher, and Zahra Hasanvand, “Cu decorated multiwalled carbon nanotubes: Application to electrocatalytic oxidation and determination of 4-nitrophenol in river water samples by square-wave voltammetry,” ADVANCES IN ENVIRONMENTAL TECHNOLOGY, vol. 4, no. 1, pp. 51–60, 2018, [Online]. Available: https://sid.ir/paper/348555/en

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