Investigation of Thermodynamic Model for Ceria Promoted Nickel Catalyst Supported on Nanocrystalline MgO in Dry Reforming of Methane

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KHAJENOORI MASOUD; MESHKANI FERESHTEH; REZAEI MEHRAN

مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

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Journal: Modeling in Engineering Year:2018 | Volume:16 | Issue:53 Page(s): 389-396

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Title

Investigation of Thermodynamic Model for Ceria Promoted Nickel Catalyst Supported on Nanocrystalline MgO in Dry Reforming of Methane

Author(s)

KHAJENOORI MASOUD | MESHKANI FERESHTEH | REZAEI MEHRAN | Issue Writer Certificate

Keywords

Nickel CatalystQ1

PromotedQ1

Cerium OxideQ1

Dry ReformingQ1

ThermodynamicQ2

Abstract

In this research paper, ceria Promoted Nickel Catalysts supported on nanocrystalline MgO were prepared and employed in methane reforming with carbon dioxide for syngas production. The textural properties of the prepared catalyst (10%Ni-7%CeO2/MgO) was characterized by the X-ray diffraction (XRD) and nitrogen adsorption (BET) techniques in order to study the crystalline phases and also the textural characteristics of this nickel based catalyst. The characterization results showed that the prepared Nickel Catalyst possessed BET area of 58/08 m2 g-1, pore volume of 0. 40 cm3 g-1 and pore size of 19. 45 nm. In addition, the Thermodynamic model was investigated using the Gibbs energy minimization method and the results were compared with experimental tests. The results confirmed that the deviation of experimental data and data predicted by the model (absolute average deviation) for methane and carbon dioxide conversions, yield of H2 and CO, H2/CO ratio were 3. 969, 1. 95, 1. 78, 2. 32 and 0. 07, respectively.

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APA: Copy

KHAJENOORI, MASOUD, MESHKANI, FERESHTEH, & REZAEI, MEHRAN. (2018). Investigation of Thermodynamic Model for Ceria Promoted Nickel Catalyst Supported on Nanocrystalline MgO in Dry Reforming of Methane. JOURNAL OF MODELING IN ENGINEERING, 16(53 ), 389-396. SID. https://sid.ir/paper/361768/en

Vancouver: Copy

KHAJENOORI MASOUD, MESHKANI FERESHTEH, REZAEI MEHRAN. Investigation of Thermodynamic Model for Ceria Promoted Nickel Catalyst Supported on Nanocrystalline MgO in Dry Reforming of Methane. JOURNAL OF MODELING IN ENGINEERING[Internet]. 2018;16(53 ):389-396. Available from: https://sid.ir/paper/361768/en

IEEE: Copy

MASOUD KHAJENOORI, FERESHTEH MESHKANI, and MEHRAN REZAEI, “Investigation of Thermodynamic Model for Ceria Promoted Nickel Catalyst Supported on Nanocrystalline MgO in Dry Reforming of Methane,” JOURNAL OF MODELING IN ENGINEERING, vol. 16, no. 53 , pp. 389–396, 2018, [Online]. Available: https://sid.ir/paper/361768/en

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