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Information Journal Paper

Title

Study on solvent extraction of REEs from a NdFeB permanent magnet scrap

Pages

  32-41

Abstract

 In this study recovery of Rare earth elements from a NdFeB magnet was investigated. The magnet was firstly demagnetized at 450° C followed by grinding and leaching in 2 M sulfuric acid, wherein the Rare earth elements were precipitated as their sodium double sulfate. However, iron and boron as the main impurities remained in the solution. The REEs double sulfate was subsequently treated with oxalic acid to obtain REEs oxalate followed by calcination of the rare-earth oxalates at 950° C for 2 hours to produce rare-earth oxides. After leaching the REEs oxide in 0. 5 M hydrochloric acid, Solvent extraction was carried out using D2EHPA as the extractant. Results showed that selective extraction of Dy is possible at pH<0. 5, while the extraction of all four elements could be achieved efficiently in higher pH values. It was observed that the heavier elements were extracted with higher efficiency compared to the light elements for all pH values examined. Under the evaluated conditions, the extraction of Nd, Pr, and Dy at pH=3 was almost completed.

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  • Cite

    APA: Copy

    KHANI, SOMAYEH, SALEHI, HOSSEIN, TAVAKOLI, HAMED, & ABOUTALEBI, MOHAMMAD REZA. (2019). Study on solvent extraction of REEs from a NdFeB permanent magnet scrap. METALLURGICAL ENGINEERING, 22(1 (73) ), 32-41. SID. https://sid.ir/paper/409409/en

    Vancouver: Copy

    KHANI SOMAYEH, SALEHI HOSSEIN, TAVAKOLI HAMED, ABOUTALEBI MOHAMMAD REZA. Study on solvent extraction of REEs from a NdFeB permanent magnet scrap. METALLURGICAL ENGINEERING[Internet]. 2019;22(1 (73) ):32-41. Available from: https://sid.ir/paper/409409/en

    IEEE: Copy

    SOMAYEH KHANI, HOSSEIN SALEHI, HAMED TAVAKOLI, and MOHAMMAD REZA ABOUTALEBI, “Study on solvent extraction of REEs from a NdFeB permanent magnet scrap,” METALLURGICAL ENGINEERING, vol. 22, no. 1 (73) , pp. 32–41, 2019, [Online]. Available: https://sid.ir/paper/409409/en

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