THE MSA AND THE INDIVIDUAL IONIC ACTIVITY COEFFICIENTS

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TAGHIKHANI VAHID; MODARES H.; KHOSHKBARCHI M.K.; VERA J.H.

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Journal Paper

Paper Information

Journal: IRANIAN JOURNAL OF SCIENCE AND TECHNOLOGY TRANSACTION B- ENGINEERING Year:2003 | Volume:27 | Issue:B2 Page(s): 247-252

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Title

THE MSA AND THE INDIVIDUAL IONIC ACTIVITY COEFFICIENTS

Author(s)

TAGHIKHANI VAHID | MODARES H. | KHOSHKBARCHI M.K. | VERA J.H.

Keywords

MEAN SPHERICAL APPROXIMATION

ACTIVITY COEFFICIENT

INDIVIDUAL IONS

AND ELECTROLYTE SOLUTIONS

Abstract

The MEAN SPHERICAL APPROXIMATION (MSA) has been applied to accurately correlate the ACTIVITY COEFFICIENTs of INDIVIDUAL IONS in aqueous solutions of single 1:1 electrolytes. In order to account for changes in the hydration of the ions, the size parameters of the ions are considered to be composition dependent. The values of the size parameters show that the hydration of the ions decreases as the electrolyte concentration increases. Results obtained from the full MSA and from a simplified version of MSA(SMSA), were compared. The use of the simplified version had a small effect on the final results and dramatically reduced the computation of the effort.

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APA: Copy

TAGHIKHANI, VAHID, MODARES, H., KHOSHKBARCHI, M.K., & VERA, J.H.. (2003). THE MSA AND THE INDIVIDUAL IONIC ACTIVITY COEFFICIENTS. IRANIAN JOURNAL OF SCIENCE AND TECHNOLOGY TRANSACTION B- ENGINEERING, 27(B2), 247-252. SID. https://sid.ir/paper/528050/en

Vancouver: Copy

TAGHIKHANI VAHID, MODARES H., KHOSHKBARCHI M.K., VERA J.H.. THE MSA AND THE INDIVIDUAL IONIC ACTIVITY COEFFICIENTS. IRANIAN JOURNAL OF SCIENCE AND TECHNOLOGY TRANSACTION B- ENGINEERING[Internet]. 2003;27(B2):247-252. Available from: https://sid.ir/paper/528050/en

IEEE: Copy

VAHID TAGHIKHANI, H. MODARES, M.K. KHOSHKBARCHI, and J.H. VERA, “THE MSA AND THE INDIVIDUAL IONIC ACTIVITY COEFFICIENTS,” IRANIAN JOURNAL OF SCIENCE AND TECHNOLOGY TRANSACTION B- ENGINEERING, vol. 27, no. B2, pp. 247–252, 2003, [Online]. Available: https://sid.ir/paper/528050/en

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