مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

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Cites:

1

Information Journal Paper

Title

MONTE CARLO SIMULATION OF NON-LINEAR FREE RADICAL POLYMERIZATION USING A PERCOLATION KINETIC GELATION MODEL (II): FREE RADICAL COPOLYMERIZATION

Pages

  355-361

Abstract

 A KINETIC GELATION MODEL that incorporates the kinetic of non-linear free radical copolymerization of a mixture of bi- and tetrafunctional monomers is used to simulate the kinetics effects on polymerization statistics and microstructures. An algorithm for random next step selection in a self-avoiding random walk and efficient mechanisms of mobility of components are introduced to improve the universality of the predictions by removing commonly occurring simulation deficiencies due to early trapping of radicals. The model has the capability to account into several free radical polymerization mechanisms such as cross-linking, branching, and also to predict the onset of sol-gel transition, and the effect of chemical composition on the transition point. It is shown that a better understanding of microstructure evolution and appearance of gel phase during polymerization and chemical gelation is attained. Finally, one important benefit of the simulation method is the ability to produce a system of very highly packed random chains or clusters within a polymer network.

Cites

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    • Cite

    APA: Copy

    GHIAS, M., DABIR, B., NIKAZAR, M., REY, A.D., & NAZOKDAST, H.. (2001). MONTE CARLO SIMULATION OF NON-LINEAR FREE RADICAL POLYMERIZATION USING A PERCOLATION KINETIC GELATION MODEL (II): FREE RADICAL COPOLYMERIZATION. IRANIAN POLYMER JOURNAL (ENGLISH), 10(6), 355-361. SID. https://sid.ir/paper/528372/en

    Vancouver: Copy

    GHIAS M., DABIR B., NIKAZAR M., REY A.D., NAZOKDAST H.. MONTE CARLO SIMULATION OF NON-LINEAR FREE RADICAL POLYMERIZATION USING A PERCOLATION KINETIC GELATION MODEL (II): FREE RADICAL COPOLYMERIZATION. IRANIAN POLYMER JOURNAL (ENGLISH)[Internet]. 2001;10(6):355-361. Available from: https://sid.ir/paper/528372/en

    IEEE: Copy

    M. GHIAS, B. DABIR, M. NIKAZAR, A.D. REY, and H. NAZOKDAST, “MONTE CARLO SIMULATION OF NON-LINEAR FREE RADICAL POLYMERIZATION USING A PERCOLATION KINETIC GELATION MODEL (II): FREE RADICAL COPOLYMERIZATION,” IRANIAN POLYMER JOURNAL (ENGLISH), vol. 10, no. 6, pp. 355–361, 2001, [Online]. Available: https://sid.ir/paper/528372/en

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