مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

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Information Journal Paper

Title

ETHYLENE/PROPYLENE COPOLYMERIZATION USING CP2ZRCL2/MAO CATALYST: EFFECTS OF COPOLYMERIZATION CONDITIONS ON VISCOSITY AVERAGE MOLECULAR WEIGHT

Pages

  15-21

Abstract

 Copolymerization of ethylene with propylene is carried out semi-continuously in toluene at atmospheric pressure and with various propylene/ethylene molar ratios. The polymerization temperature and cocatalyst/catalyst molar ratio were also varied in a wide range. Cp2ZrCl2/MAO System was used as catalyst. The VISCOSITY AVERAGE MOLECULAR WEIGHTs of copolymers obtained were determined by measuring the intrinsic viscosity [ h] and application of the Mark-Houwink equation. The values of molecular weights were found to be dependent on operating conditions except on polymerization time in the range 5-30 min. increasing the polymerization temperature, propylene/ethylene and cocatalyst/catalyst molar ratios caused a continuous decrease in molecular weight. An important reason for this effect was shown to be accelerated CHAIN TRANSFER REACTIONs.

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  • Cite

    APA: Copy

    SOBHAN MANESH, K., & HAJIZADEH, AHMAD. (2005). ETHYLENE/PROPYLENE COPOLYMERIZATION USING CP2ZRCL2/MAO CATALYST: EFFECTS OF COPOLYMERIZATION CONDITIONS ON VISCOSITY AVERAGE MOLECULAR WEIGHT. IRANIAN POLYMER JOURNAL (ENGLISH), 14(1 (55)), 15-21. SID. https://sid.ir/paper/529569/en

    Vancouver: Copy

    SOBHAN MANESH K., HAJIZADEH AHMAD. ETHYLENE/PROPYLENE COPOLYMERIZATION USING CP2ZRCL2/MAO CATALYST: EFFECTS OF COPOLYMERIZATION CONDITIONS ON VISCOSITY AVERAGE MOLECULAR WEIGHT. IRANIAN POLYMER JOURNAL (ENGLISH)[Internet]. 2005;14(1 (55)):15-21. Available from: https://sid.ir/paper/529569/en

    IEEE: Copy

    K. SOBHAN MANESH, and AHMAD HAJIZADEH, “ETHYLENE/PROPYLENE COPOLYMERIZATION USING CP2ZRCL2/MAO CATALYST: EFFECTS OF COPOLYMERIZATION CONDITIONS ON VISCOSITY AVERAGE MOLECULAR WEIGHT,” IRANIAN POLYMER JOURNAL (ENGLISH), vol. 14, no. 1 (55), pp. 15–21, 2005, [Online]. Available: https://sid.ir/paper/529569/en

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