POLY(ACRYLIC ACID) TEMPLATE-GUIDED ENZYMATIC SYNTHESIS OF WATER-SOLUBLE POLY(O-TOLUIDINE)

Q: How can I download an article?

To download an article from SID, first log in to the site, search for the article title, and click on the 'Download Article' option.

Q: How can I download an ISI article?

To download an ISI article on SID, enter the keyword or article title in the search bar, view the relevant results, click on the desired article, and select the 'Download Article' option.

Q: How can I access the SID database?

To access the SID database, visit SID.ir, create an account, and log in to access scientific resources.

Q: Is downloading articles from SID free?

Some articles on SID are available for free, while others require payment. Details are specified on the article's page.

NABID M.R.; SEDGHI ROUYA; ENTEZAMI A.A.

مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

Journal Paper

Paper Information

Journal: Iranian Polymer Journal Year:2006 | Volume:15 | Issue:5 (71) Page(s): 417-423

Download Full-Text

View:

314

Download:

276

Cites:

Information Journal Paper

Title

POLY(ACRYLIC ACID) TEMPLATE-GUIDED ENZYMATIC SYNTHESIS OF WATER-SOLUBLE POLY(O-TOLUIDINE)

Author(s)

NABID M.R. | SEDGHI ROUYA | ENTEZAMI A.A. | Issue Writer Certificate

Keywords

TEMPLATE-GUIDED

HORSERADISH PEROXIDASE

WATER-SOLUBLE

POLY(O-TOLUIDINE)

CONDUCTING POLYMER

Abstract

It was recently reported that WATER-SOLUBLE conducting polyaniline may be prepared using a new TEMPLATE-GUIDED enzymatic approach. It was found that the template provides a necessary type of local environment where the pH and charge density near the template molecules are different from that of the bulk solution. A strong acid polyelectrolyte, such as sulphonated polystyrene (SPS), is the most favourable because it provides a lower, local pH environment that serves to both charges and preferentially align the monomers through electrostatic and hydrophobic interactions to promote the desirable head-to-tail coupling. Poly (acrylic acid) (PAA) partial sodium salt is used as an acid polyelectrolyte in this work. Biocatalytic polymerization using a naturally occurring enzyme is advantageous because it is a simple, one-step and environmentally compatible method. The HORSERADISH PEROXIDASE (HRP) enzyme is used in polymerization of o-toluidine in the presence of poly (acrylic acid) partial salt as a template and camphor sulphonic acid as a dopant. The synthesis is simple and the conditions are mild. Best results are obtained in pH 4.3 phosphates buffered aqueous solutions with stoichiometric amount of monomer, template and oxidant and catalytic amount of enzyme. The synthesized polymers have been characterized by UV-vis and FTIR spectroscopy and cyclic voltammetry. These studies confirm that electroactive and conducting forms of poly (o-toluidine) (POT) are obtained in the presence of PAA.

Cites

No record.

References

No record.

Cite

APA: Copy

NABID, M.R., SEDGHI, ROUYA, & ENTEZAMI, A.A.. (2006). POLY(ACRYLIC ACID) TEMPLATE-GUIDED ENZYMATIC SYNTHESIS OF WATER-SOLUBLE POLY(O-TOLUIDINE). IRANIAN POLYMER JOURNAL (ENGLISH), 15(5 (71)), 417-423. SID. https://sid.ir/paper/531622/en

Vancouver: Copy

NABID M.R., SEDGHI ROUYA, ENTEZAMI A.A.. POLY(ACRYLIC ACID) TEMPLATE-GUIDED ENZYMATIC SYNTHESIS OF WATER-SOLUBLE POLY(O-TOLUIDINE). IRANIAN POLYMER JOURNAL (ENGLISH)[Internet]. 2006;15(5 (71)):417-423. Available from: https://sid.ir/paper/531622/en

IEEE: Copy

M.R. NABID, ROUYA SEDGHI, and A.A. ENTEZAMI, “POLY(ACRYLIC ACID) TEMPLATE-GUIDED ENZYMATIC SYNTHESIS OF WATER-SOLUBLE POLY(O-TOLUIDINE),” IRANIAN POLYMER JOURNAL (ENGLISH), vol. 15, no. 5 (71), pp. 417–423, 2006, [Online]. Available: https://sid.ir/paper/531622/en

Related Journal Papers

No record.

Related Seminar Papers

No record.

Related Plans

No record.

Recommended Workshops