RADIATION-INDUCED CHEMICAL SYNTHESIS OF CARRIERS OF BIOLOGICALLY ACTIVE COMPOUNDS: COPOLYMERS OF N-VINYL-2-PYRROLIDONE WITH ALLYL ALCOHOL AND ALLYL AMINE

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SOLOVSKIJ M.V.; GUDAITIS A.A.; BOIMIRZAEV A.S.; NESTEROV V.V.; PANARIN E.F.

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Journal: Iranian Polymer Journal Year:2001 | Volume:10 | Issue:6 Page(s): 347-354

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Title

RADIATION-INDUCED CHEMICAL SYNTHESIS OF CARRIERS OF BIOLOGICALLY ACTIVE COMPOUNDS: COPOLYMERS OF N-VINYL-2-PYRROLIDONE WITH ALLYL ALCOHOL AND ALLYL AMINE

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Keywords

RADIATION

COPOLYMERIZATION

COPOLYMER-CARRIERS OF BIOLOGICALLY ACTIVE COMPOUNDS

N-VINYL-2-PYRROLIDONE

ALLYL ALCOHOL

ALLYL AMINE

Abstract

RADIATION-induced COPOLYMERIZATION is a very promising method for the synthesis of polymers with the required combination of properties. It provides the possibility of controlling the COPOLYMERIZATION process and, thus, to obtain copolymers with the desired composition and molecular weight characteristics as well as copolymers with comonomers that are difficult to polymerize. This work deals with the characterization of RADIATION-induced COPOLYMERIZATION of N-VINYL-2-PYRROLIDONE (VP) with such comonomers: ALLYL ALCOHOL and allylamine in bulk, in ethanol or isopropanol at 320 K and at an irRADIATION dose rate of 2 Gyls. It was established that by changing the characteristics of the irradiated medium (irRADIATION dose, composition and concentration of the initial monomer mixture and solvent nature) it is possible to obtain water-soluble reactive copolymers of VP with ALLYL ALCOHOL and allylamine. Their molecular weights, Mw, are between 10-68x103, their molecular weight distribution is relatively narrow (MW/ Mn=1 .4-2.8) and they contain 12 .8-24.3 mol % of functional groups. The structure of these copolymers was confirmed by functional analysis and IR spectroscopy, Acute toxicity of these functional copolymers was investigated. Some of these copolymers in their principal characteristic meet the requirements that should be fulfilled by synthetic non-biodegradable polymers, modifiers of biologically active compounds. Specific examples are reported in using them as carriers of biologically active compounds with fungicidal activity.

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APA: Copy

SOLOVSKIJ, M.V., GUDAITIS, A.A., BOIMIRZAEV, A.S., NESTEROV, V.V., & PANARIN, E.F.. (2001). RADIATION-INDUCED CHEMICAL SYNTHESIS OF CARRIERS OF BIOLOGICALLY ACTIVE COMPOUNDS: COPOLYMERS OF N-VINYL-2-PYRROLIDONE WITH ALLYL ALCOHOL AND ALLYL AMINE. IRANIAN POLYMER JOURNAL (ENGLISH), 10(6), 347-354. SID. https://sid.ir/paper/535076/en

Vancouver: Copy

SOLOVSKIJ M.V., GUDAITIS A.A., BOIMIRZAEV A.S., NESTEROV V.V., PANARIN E.F.. RADIATION-INDUCED CHEMICAL SYNTHESIS OF CARRIERS OF BIOLOGICALLY ACTIVE COMPOUNDS: COPOLYMERS OF N-VINYL-2-PYRROLIDONE WITH ALLYL ALCOHOL AND ALLYL AMINE. IRANIAN POLYMER JOURNAL (ENGLISH)[Internet]. 2001;10(6):347-354. Available from: https://sid.ir/paper/535076/en

IEEE: Copy

M.V. SOLOVSKIJ, A.A. GUDAITIS, A.S. BOIMIRZAEV, V.V. NESTEROV, and E.F. PANARIN, “RADIATION-INDUCED CHEMICAL SYNTHESIS OF CARRIERS OF BIOLOGICALLY ACTIVE COMPOUNDS: COPOLYMERS OF N-VINYL-2-PYRROLIDONE WITH ALLYL ALCOHOL AND ALLYL AMINE,” IRANIAN POLYMER JOURNAL (ENGLISH), vol. 10, no. 6, pp. 347–354, 2001, [Online]. Available: https://sid.ir/paper/535076/en

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