PREPARATION AND CHARACTERIZATION OF CONDUCTING POLYMER LATICES BY CHEMICAL POLYMERIZATION OF ANILINE OR ANISIDINE IN PRESENCE OF LATEX: STUDY OF THEIR ELECTROACTIVITY AND ANTI-CORROSION PROPERTIES

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MASSOUMI BAKHSHALI; BADALKHANI OMMOLBANIN

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Journal Paper

Paper Information

Journal: Iranian Journal of Polymer Science and Technology Year:2013 | Volume:26 | Issue:4 (ISSUE NO. 126) Page(s): 318-325

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Title

PREPARATION AND CHARACTERIZATION OF CONDUCTING POLYMER LATICES BY CHEMICAL POLYMERIZATION OF ANILINE OR ANISIDINE IN PRESENCE OF LATEX: STUDY OF THEIR ELECTROACTIVITY AND ANTI-CORROSION PROPERTIES

Author(s)

MASSOUMI BAKHSHALI | BADALKHANI OMMOLBANIN | Issue Writer Certificate

Keywords

CONDUCTING-LATEX POLYMERQ2

POLY (VINYLACETATE-CO-BUTYL METHACRYLATE)Q2

POLYANILINEQ1

POLYANISIDINEQ2

ANTI-CORROSION COATINGQ3

Abstract

Poly (vinyl acetate-co-butyl methacrylate) was prepared in presence of potassium persulphate as an oxidizing agent in aqueous solution of dodecyl benzene sulfonate sodium as an emulsifying agent. Then, aniline was polymerized by chemical oxidation method at three different concentrations of aniline monomer (0.1, 0.2 and 0.3 M) in toluene in presence of poly (vinylacetate-co-butyl methacrylate) in order to obtain POLYANILINE/poly (vinylacetate-co-butyl methacrylate). To prepare conducting-latex of POLYANISIDINE/poly (vinyl acetate-co-butyl methacrylate) the same method was employed as above for aniline monomer in obtaining conducting POLYANILINE/poly (vinylacetate-co-butyl methacrylate) latex. In addition, the purification of CONDUCTING-LATEX POLYMERs, POLYANILINE/poly (vinylacetate-co-butyl methacrylate) and POLYANISIDINE/poly (vinylacetate-co-butyl methacrylate) was conducted and preparation of tin layer films of CONDUCTING-LATEX POLYMERs was carried out by casting method on glassy lames. The electro activity properties of the prepared latex polymers, POLYANILINE/poly (vinylacetate-co-butyl methacrylate) and POLYANISIDINE/ poly (vinylacetate-co-butyl methacrylate) were investigated by cyclic voltammetery (CV). The voltamogrames showed that the latex films were electro active. Because of conductivity and electro activity, the obtained films may find applications in anticorrosion coatings. The anti-corrosion properties of CONDUCTING-LATEX POLYMERs were studied on aluminum surface by impedance technique. The structure of the prepared CONDUCTING-LATEX POLYMERs was confirmed by Fourier transform infrared (FTIR). Finally, the electrical conductivity of synthesized CONDUCTING-LATEX POLYMERs, POLYANILINE/poly (vinylacetate-co-butyl methacrylate) and POLYANISIDINE/ poly (vinylacetate-co-butyl methacrylate) was measured by four probe technique.

Cites

بررسی و بهبود رسانایی پلی (3، 4- اتیلن دی اکسی تیوفن): پلی (استایرن سولفونیک اسید) (PEDOT:PSS) با افزودن نانوذرات نقره و مایع یونی 2-متیل ایمیدازولیوم

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APA: Copy

MASSOUMI, BAKHSHALI, & BADALKHANI, OMMOLBANIN. (2013). PREPARATION AND CHARACTERIZATION OF CONDUCTING POLYMER LATICES BY CHEMICAL POLYMERIZATION OF ANILINE OR ANISIDINE IN PRESENCE OF LATEX: STUDY OF THEIR ELECTROACTIVITY AND ANTI-CORROSION PROPERTIES. IRANIAN JOURNAL OF POLYMER SCIENCE AND TECHNOLOGY (PERSIAN), 26(4 (ISSUE NO. 126)), 318-325. SID. https://sid.ir/paper/6389/en

Vancouver: Copy

MASSOUMI BAKHSHALI, BADALKHANI OMMOLBANIN. PREPARATION AND CHARACTERIZATION OF CONDUCTING POLYMER LATICES BY CHEMICAL POLYMERIZATION OF ANILINE OR ANISIDINE IN PRESENCE OF LATEX: STUDY OF THEIR ELECTROACTIVITY AND ANTI-CORROSION PROPERTIES. IRANIAN JOURNAL OF POLYMER SCIENCE AND TECHNOLOGY (PERSIAN)[Internet]. 2013;26(4 (ISSUE NO. 126)):318-325. Available from: https://sid.ir/paper/6389/en

IEEE: Copy

BAKHSHALI MASSOUMI, and OMMOLBANIN BADALKHANI, “PREPARATION AND CHARACTERIZATION OF CONDUCTING POLYMER LATICES BY CHEMICAL POLYMERIZATION OF ANILINE OR ANISIDINE IN PRESENCE OF LATEX: STUDY OF THEIR ELECTROACTIVITY AND ANTI-CORROSION PROPERTIES,” IRANIAN JOURNAL OF POLYMER SCIENCE AND TECHNOLOGY (PERSIAN), vol. 26, no. 4 (ISSUE NO. 126), pp. 318–325, 2013, [Online]. Available: https://sid.ir/paper/6389/en

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