REGIOSELECTIVE AZIDOLYSIS OF EPOXIDES IN WATER USING POLY(VINYLAMINE) AND POLY(ALLYLAMINE) AS NEW POLYMERIC COSOLVENTS

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TAMAMI B.; KOLAHDOUZAN MOHSEN; MAHDAVI H.

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Journal: Iranian Polymer Journal Year:2004 | Volume:13 | Issue:1 Page(s): 21-28

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Title

REGIOSELECTIVE AZIDOLYSIS OF EPOXIDES IN WATER USING POLY(VINYLAMINE) AND POLY(ALLYLAMINE) AS NEW POLYMERIC COSOLVENTS

Author(s)

TAMAMI B. | KOLAHDOUZAN MOHSEN | MAHDAVI H. | Issue Writer Certificate

Keywords

POLY(VINYLAMINE)Q4

POLY(ALLYLAMINE)Q4

POLYMERIC COSOLVENTQ4

EPOXIDEQ4

AZIDOHYDRINEQ4

Abstract

The toxic and volatile nature of many organic solvents that are widely used in organic synthesis have posed a serious threat to the environment. One of the recently developed methods is to use water as solvent. However, its use is limited by the low solubility of organic compounds. One of the most important strategies to overcome this limitation of water is the utilization of organic cosolvents. Thus, as new POLYMERIC COSOLVENTs poly (vinyl amine) (PVA) and poly (allylamine) (PAA) were prepared and used as cosolvent/catalyst systems in the regioselective ring opening of EPOXIDE by azide ion in water at room temperature to give AZIDOHYDRINE in excellent yield under mild reaction conditions. These polymeric catalysts can be used several times without any loss in their activity.

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APA: Copy

TAMAMI, B., KOLAHDOUZAN, MOHSEN, & MAHDAVI, H.. (2004). REGIOSELECTIVE AZIDOLYSIS OF EPOXIDES IN WATER USING POLY(VINYLAMINE) AND POLY(ALLYLAMINE) AS NEW POLYMERIC COSOLVENTS . IRANIAN POLYMER JOURNAL (ENGLISH), 13(1), 21-28. SID. https://sid.ir/paper/85896/en

Vancouver: Copy

TAMAMI B., KOLAHDOUZAN MOHSEN, MAHDAVI H.. REGIOSELECTIVE AZIDOLYSIS OF EPOXIDES IN WATER USING POLY(VINYLAMINE) AND POLY(ALLYLAMINE) AS NEW POLYMERIC COSOLVENTS . IRANIAN POLYMER JOURNAL (ENGLISH)[Internet]. 2004;13(1):21-28. Available from: https://sid.ir/paper/85896/en

IEEE: Copy

B. TAMAMI, MOHSEN KOLAHDOUZAN, and H. MAHDAVI, “REGIOSELECTIVE AZIDOLYSIS OF EPOXIDES IN WATER USING POLY(VINYLAMINE) AND POLY(ALLYLAMINE) AS NEW POLYMERIC COSOLVENTS ,” IRANIAN POLYMER JOURNAL (ENGLISH), vol. 13, no. 1, pp. 21–28, 2004, [Online]. Available: https://sid.ir/paper/85896/en

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