Mechanism and Compatibilization Effect of Nanoparticles in Polymer Blends

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Abzan Mohammad Soroush; AHMADI SHERVIN; Mirzaee Ramin

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Journal Paper

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Journal: POLYMERIZATION Year:2022 | Volume:11 | Issue:4 Page(s): 3-15

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Title

Mechanism and Compatibilization Effect of Nanoparticles in Polymer Blends

Author(s)

Abzan Mohammad Soroush | AHMADI SHERVIN | Mirzaee Ramin | Issue Writer Certificate

Keywords

polymer blends

compatibilization

nanoparticles

interface

3D network

Abstract

Blending of polymers is one of the useful methods for developing polymeric materials with improved properties or creating special properties in polymers. The mixture of some polymers is completely or partially miscible, but the mixture of many polymers is immiscible and their microstructure will be multiphase due to high molecular weight and undesirable interactions. Extensive research has been conducted on the development of blend compatibilization approaches. Surface modification of polymers, addition of block copolymers, reactive compatibilization, crosslinking, interpenetrating networks, and more recently the addition of fillers in the micro and nano dimensions are some of the methods used to improve the compatibility of mixtures. The reduction of modulus and its related properties, when adding polymeric compatibilizers has caused researchers to pay more attention to nanoparticles and their compatibility effect. Compatibility mechanisms of polymer blends using nanoparticles can be divided into two modes based on their location in the blend. First, nanoparticles in the matrix phase, by forming a three-dimensional network and increasing the viscosity, apply more stress to the dispersed phase, reduce the size of the dispersed regions, and then reduce the coalescence phenomena of dispersed particles. In the second case, the nanoparticles, by locating at the interface between the matrix and dispersed phases reduce the interfacial stress and increase the interfacial adhesion. Also, in this case, they prevent the integration of scattered phase droplets. In this paper, the effect of nanoparticle compatibility on polymer blends, mechanisms, and the affecting structural factors are reviewed.

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APA: Copy

Abzan, Mohammad Soroush, AHMADI, SHERVIN, & Mirzaee, Ramin. (2022). Mechanism and Compatibilization Effect of Nanoparticles in Polymer Blends. POLYMERIZATION, 11(4 ), 3-15. SID. https://sid.ir/paper/985974/en

Vancouver: Copy

Abzan Mohammad Soroush, AHMADI SHERVIN, Mirzaee Ramin. Mechanism and Compatibilization Effect of Nanoparticles in Polymer Blends. POLYMERIZATION[Internet]. 2022;11(4 ):3-15. Available from: https://sid.ir/paper/985974/en

IEEE: Copy

Mohammad Soroush Abzan, SHERVIN AHMADI, and Ramin Mirzaee, “Mechanism and Compatibilization Effect of Nanoparticles in Polymer Blends,” POLYMERIZATION, vol. 11, no. 4 , pp. 3–15, 2022, [Online]. Available: https://sid.ir/paper/985974/en

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