In the present study, the feasibility of a-Fe ferromagnetic phase formation in GLASS and GLASS-ceramic by reduction in hydrogen atmosphere have been investigated. The GLASS with the composition of 35Na2O-24Fe2O3-20B2O3 20SiO2-z-1ZnO (mol %) was melted and quenched by using a twin roller technique. As quenched GLASS flakes were heat treated in the range of 400-675 °C for 1-2 h in hydrogen atmosphere, which resulted in reduction of iron cations to a-Fe and FeO. The reduction of iron cations in GLASS was not completely occurred. Saturation magnetization of these samples was 8-37 emu g -1 For the formation of GLASS ceramic, As quenched GLASS flakes heat treated at 590 °C for 1 h. Heat treatment of GLASS ceramic containing magnetite at 675°C in hydrogen atmosphere for 1 h led to reduction of almost all of the iron cations to a-Fe. Saturation magnetization of this sample increased from 19.8 emu g -1 for GLASS ceramic to 67 emu g-1.