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Writer: 

Journal: 

داخلی

Issue Info: 
  • End Date: 

    اسفند ماه 1379
Measures: 
  • Citations: 

    4
  • Views: 

    863
  • Downloads: 

    0
Keywords: 
Abstract: 

کراتینین عبارت از کراتین بدون آب است که به صورت محلول زائد توسط کلیه دفع می گردد. غلظت کراتینین در خون همچون اوره با کاهش فعالیت کلیه افزایش می یابد. با انسداد مجرای ادرار و در نفریت مزمن غلظت کراتینین ممکن است به نسبت بیش از مقدار اوره باشد. در اختلال رشدعضلانی مقدار کراتینین کاهش می یابد. اندازه گیری مقدار کراتینین در خون و ادرار جهت تشخیص بیماری های فوق در آزمایشگاههای تشخیص طبی رایج است. در این طرح دو نوع معرف کراتینین طراحی و ساخته شده است.یکی به روش Kinetic که درمدت کمتر از دو دقیقه کراتینین را می توان توسط آن اندازه گیری نمود، دیگری معرف ساخته شده به روش End Point است که در آن چندین نمونه را در فرصت مناسب (پایان واکنش) می توان اندازه گیری نمود. این معرف طوری طراحی شده است که جواب مثبت کاذب نمی دهد و از دقت خیلی خوبی برخوردار است. ساخت این کیت ها جهت تامین نیاز آزمایشگاههای تشخیص طبی کشور می باشد.

Yearly Impact:   مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

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Issue Info: 
  • Year: 

    2014
  • Volume: 

    20
Measures: 
  • Views: 

    172
  • Downloads: 

    70
Keywords: 
Abstract: 

MODEL-BASED LEAST SQUARES FITTING ANALYSIS OR HARD MODELING IS A SPECIFIC PART OF CHEMOMETRICS, WHICH IS BASED ON MATHEMATICAL RELATIONSHIPS FOR DESCRIBING THE MEASUREMENTS [1]. FURTHERMORE, MODEL-BASED ANALYSIS OF COUPLED EQUILIBRIUM-KINETIC PROCESSES IS THE COMPUTATION OF THE CONCENTRATIONS OF ALL CHEMICAL SPECIES AS A FUNCTION OF THE PROGRESS OF AN INTERTWINED KINETICEQUILIBRIUM CHEMICAL PROCESS. THIS MEANS EQUILIBRIUM PROCESSES HAVE BEEN DIRECTLY INCORPORATED INTO THE RATE LAWS [2]. IN THIS STUDY, WE DEMONSTRATE SEVERAL MODELS, THAT THEY CAN BE APPLIED TO NUMEROUS CHEMICAL MECHANISMS. THERE ARE SEVERAL DIFFERENT TYPES OF INTERTWINED KINETICEQUILIBRIUM CHEMICAL PROCESSES THAT CAN BE MODELED, COMMON EXAMPLES, MODELED IN THIS WORK, INCLUDE CHARGE TRANSFER COMPLEX FORMATION REACTIONS, PH_DEPENDENT DEGRADATION OF CHEMICAL COMPOUNDS, KINETIC OF COMPLEXATION REACTION AT VARIABLE PH AND TAUTOMERIZATION KINETICS IN MICELLAR SOLUTIONS. ACTUALLY, WE HAVE RESTRICTED OURSELVES TO CHEMICAL REACTIONS WHERE BOTH EQUILIBRIUM AND KINETIC PROCEDURES ARE LINKED WITH EACH OTHER. THE GOAL IS TO DEMONSTRATE HOW THE CONCENTRATIONS OF ALL REACTING SPECIES CAN BE COMPUTED AS A FUNCTION OF TIME FOR ANY REACTION MECHANISM USING THE KINETIC DATA. IT IS RELATIVELY STRAIGHTFORWARD TO INCORPORATE AN APPROPRIATE ALGORITHM INTO A GENERAL NON-LINEAR LEAST-SQUARES ROUTINE FOR THE INVESTIGATED DATA. THE CALCULATIONS ARE BASED ON THE KNOWN INITIAL CONCENTRATIONS OF THE COMPONENTS AS WELL AS ALL ESTIMATED RATE AND EQUILIBRIUM CONSTANTS. AFTER THE DATA FITTING PROCESS, THE OPTIMAL PARAMETERS TOGETHER WITH AN ESTIMATE OF THEIR STANDARD DEVIATIONS HAVE BEEN OBTAINED. SUCH MODELS ALLOW THE FITTING OF THE RATE AS WELL AS THE EQUILIBRIUM CONSTANTS. MODEL-BASED ANALYSIS TOGETHER WITH THE POSSIBILITY OF CALCULATING AND INCORPORATING THE EQUILIBRIUM AND KINETIC PARAMETERS INTO THE FITTING ALGORITHM HAS ALLOWED THE COMPLETE ANALYSIS OF COMPLEX REACTION MECHANISMS. THIS IS THE FIRST COMPREHENSIVE STUDY OF ALL OF THESE LINKED REACTIONS, THEIR KINETIC CONSTANTS, AND THUS THEIR EQUILIBRIUM CONSTANTS. THIS STUDY OPENS UP A PROMISING NEW AVENUE FOR OBTAINING EQUILIBRIUM AND KINETIC CONSTANTS, SIMULTANEOUSLY, USING THE SAME KINETIC DATA.

Yearly Impact:   مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

View 172

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Issue Info: 
  • Year: 

    2022
  • Volume: 

    12
  • Issue: 

    2
  • Pages: 

    115-125
Measures: 
  • Citations: 

    0
  • Views: 

    50
  • Downloads: 

    17
Abstract: 

The development of an appropriate kinetic model for cracking reactions is essential for simulation and process optimization. These results are to be potentially used for proper reactor design. The complexities of oil gas inlet combinations have led to an increase in the challenges while defining and depicting kinetics on an intrinsic scale. Hence, complicated chemical reaction circumstances are characterized by combining many possible pathways into more modest groups of comparable chemical substances. In addition, cracking kinetic demonstrations is frequently carried out in lumped forms. This is due to the complex nature of the feedstock, which is known to contain enormous hydrocarbon associated with series and parallel reaction networks. The representation of complicated compounds by consolidating a large chemical component into small amounts of apparent components has been generally utilized in industry to generate a straightforward approach to stoichiometry, thermodynamics, and kinetics. Considering the importance of this lumped method, this study focused on studying the development of a kinetic lump approach to solve kinetic problems and cracking mechanisms.

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Issue Info: 
  • Year: 

    2003
  • Volume: 

    16
  • Issue: 

    1 (TRANSACTIONS A: BASICS)
  • Pages: 

    61-72
Measures: 
  • Citations: 

    0
  • Views: 

    348
  • Downloads: 

    0
Abstract: 

The relationship between velocity of chemical reactions with activities or concentrations of their reactants, temperature and pressure and the mechanisms through which the reactions proceed are of interest to many scientists and engineers. The purpose of this article is to introduce computer software that is developed for calculation, classification and collection of such data. The application of the software to the homogeneous and heterogeneous processes occurring in porous and non-porous media of flat, cylindrical or spherical geometry is tested. The software is capable of assisting the professional process design engineers as well as the general process kinetic investigators

Yearly Impact: مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

View 348

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Author(s): 

SIROVICH L.

Journal: 

PHYSICS OF FLUIDS

Issue Info: 
  • Year: 

    1962
  • Volume: 

    5
  • Issue: 

    8
  • Pages: 

    908-918
Measures: 
  • Citations: 

    1
  • Views: 

    138
  • Downloads: 

    0
Keywords: 
Abstract: 

Yearly Impact: مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

View 138

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Issue Info: 
  • Year: 

    2007
  • Volume: 

    26
  • Issue: 

    3
  • Pages: 

    133-140
Measures: 
  • Citations: 

    0
  • Views: 

    1008
  • Downloads: 

    0
Abstract: 

Kinetic study of dehydrogenation of isobutane to isobutene was investigated on Pt-Sn supported on g-Al2O3 as catalyst using a tubular quartz glass reactor at atmospheric pressure and a temperature range of 425-575 cc. Different rate models were extracted by considering different elementary reactions of a probable mechanism as rate controlling step and the experimental results. The adsorption and kinetic coefficients were obtained by the Levenberg-Marquardt non-linear regression applied to the reaction rate equations using the experimental results. Results from statistical investigation of the models and comparison of their error percentages indicate that a power law rate equation is in a good agreement with the experimental data obtained at 575°C.

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Author(s): 

COATS A.W. | REDFERN J.P.

Journal: 

NATURE

Issue Info: 
  • Year: 

    1964
  • Volume: 

    201
  • Issue: 

    1
  • Pages: 

    68-69
Measures: 
  • Citations: 

    1
  • Views: 

    310
  • Downloads: 

    0
Keywords: 
Abstract: 

Yearly Impact: مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

View 310

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Issue Info: 
  • Year: 

    2013
  • Volume: 

    16
Measures: 
  • Views: 

    132
  • Downloads: 

    65
Abstract: 

INTRODUCTION: TITANIUM DIOXIDE (TIO2) PHOTOCATALYSIS HAS BECOME AN INTERESTING FIELD OF RESEARCH GRUP [1]. WHEN AN INCIDENT PHOTON IS ABSORBED BY TIO2, ELECTRON IS EXCITED FROM THE VALENCE BAND TO THE CONDUCTION BAND AND CREATED POSITIVE HOLE IN THE VALENCE BAND. THE HOLE IS CAPABLE OF OXIDIZING MANY ADSORBED ORGANIC COMPOUNDS. PHOTOCATALYTIC REDUCTION OF ORGANIC COMPOUNDS OVER TIO2 HAS BEEN WIDELY STUDIED AS AN EFFICIENT TECHNIQUE FOR WATER AND AIR PURIFICATION [2]. THIS IS BECAUSE A VARIETY OF ORGANIC POLLUTANTS CAN BE DEGRADED OVER IRRADIATION OF TIO2.

Yearly Impact:   مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

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Author(s): 

SHANKAR P.N.

Issue Info: 
  • Year: 

    1970
  • Volume: 

    40
  • Issue: 

    -
  • Pages: 

    385-385
Measures: 
  • Citations: 

    1
  • Views: 

    139
  • Downloads: 

    0
Keywords: 
Abstract: 

Yearly Impact: مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

View 139

مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic ResourcesDownload 0 مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic ResourcesCitation 1 مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic ResourcesRefrence 0
Issue Info: 
  • Year: 

    2006
  • Volume: 

    3
  • Issue: 

    9
  • Pages: 

    61-69
Measures: 
  • Citations: 

    0
  • Views: 

    372
  • Downloads: 

    184
Abstract: 

In this paper, first, we present a kinetic data structure for the problem of kinetic convex hull maintenance. After that, discuss some complicated cases followed by the main algorithm and two additional algorithms. Finally, focus on the evaluation of the four properties of the kinetic algorithm in the worst case. We show that quality factors of our algorithm are at most linear. Comparing with similar work, our suggestion is easier to implement and keep track of.

Yearly Impact: مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

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