Tungsten carbide is one of semented carbide materials, that are known as metal carbides. Tungsten and carbon are the elements of WC, W2C and W5C3 that is stable only at higher than 2535°C. Among above mentioned three combinations of Tungsten, the stability of mono Tungsten carbide (WC) that briefly named Tungsten carbide is better, so, it is more important. The plasticity of Tungsten carbide is high and in comparison with steel its modulus of elasticity is three times bigger. Its hardness is bigger than that of steel, even in very stream conditions, so that it doesn't make any noticeable changes at high temperature. Because of its high resistance to wear and good shock ness, it is used in various kinds of carbide dies and cutting tools. Although the machining of Tungsten carbide with conventional methods is almost successful in comparison with machining of Silicon carbide, but because of complexity of the shape of work piece and high needed accuracy in machining, the conventional machining methods cannot achieve them. Among non-conventional machining methods EDM is an especial case in machining of cemented 'carbides. With consideration of instability of ED machining of Tungsten carbide process, this paper tries to give some instructions that leads to more stable machining process. About the machining of different grades of Tungsten - carbide, open circuit pulses are more than 50% and Arcing are less than 15% with different pulse durations. In these materials, increasing the pulse duration, increases machining instability. In nearly all grades of Tungsten- carbide, the size of the grains on the machined surfaces become bigger and show the gathering much more resolidified materials. The presence of cobalt nearly on everywhere of the machined surface patterns, may be because of resolidification of cobalt and recombination with Tungsten or Tungsten - carbide on the surface of the work piece. The elimination of the cobalt and Tungsten together from arcing area, make holes which are suitable places for carbon to remain and grow and afterwards make arcing.