Several new poly(benzimidazole-co-urea)s were synthesized. In the first step; by reaction between different tetraamines and p-aminobenzoic acid or o-aminobenzoic acid some heterocyclic diamines were obtained. In the second step, these diamines, and two different diisocyanates were used and the produced copolymers were characterized for structural determinations. The two model compounds exhibited or showed some characteristics attributed to polymers, which were confirmed and characterized by IR and 1HNMR.Heat resistance of our copolymers was lower in comparison to benzimidazole, but higher in comparison to polyureas. The solubilities, UV absorption, inherent viscosity and thermal analysis of copolymers were studied as well.