مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

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مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

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Title

Production of mid-distillation fuels from syngas using cobalt nanocatalyst supported on Gracilaria gracilis macroalgae biochar

Pages

  38-53

Abstract

 This study investigates the application of Biochar from the macroalgae Pyrolysis of Gracylaria gracilis as catalyst support for the production of mid-distillation fuels. Macroalgae were pyrolyzed at 550 °C, and the resulting products were evaluated. The major product of the Pyrolysis was Biochar (40.1%). The gaseous product mostly contained carbon dioxide (51.9%) and hydrogen (26.3%), and the liquid product mainly contained oxygenate and nitrogenate compounds. The abtained Biochar was activated and impregnated with 15% cobalt and then used as a catalyst in the Fisher-Tropesh process under conditions of syngas flow of 45 ml/min (H2/CO = 2), 18 bar pressure and temperature of 220 °C. The results showed that carbon monoxide conversion was 64.2%, and the highest product selectivity was for heavy hydrocarbons (74%), while the selectivity of carbon dioxide as a by-product was 2.3%. Catalyst characterization was performed by BET, XRD, TPR, TGA and TEM methods.

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