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Title

SYNTHESIS OF 2, 4, 6, 8, 10, 12-HEXABENZYL-2, 4, 6, 8, 10, 12-HEXAAZATETRACYCLO [5, 5, 0, 03, 11, 05, 9] DODECANE VIA NEW CATALYSTS

Pages

  3-7

Keywords

2Q3
4Q3
6Q3
8Q3
10Q3
4Q3
6Q3
8Q3
10Q3
12-HEXAAZATETRACYCLO [5Q3
5Q3
0Q3
0 3Q3
11Q3
05Q3
9] DODECANEQ3
BF3Q3

Abstract

 CL-20 is the most energetic conventional explosive available for military use. The over all aim of the high energy material research community is to increase the yield and reduce the cost of CL-20 synthesis. All synthetic methods used to prepare the CL-20, depended on the condensation reaction of benzylamine with glyoxal for the preparation of HBIW intermediate. In the presence of HCOOH catalyst and ethanol solvent, yield of 58% is reported. In this paper we investigated the effect of lewis acid catalyst on the yield of HBIW. The results showed that the more efficient catalyst such as BF3 and Mg (ClO4)2, increased the yield, 20% more than previously reported.

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    APA: Copy

    BAYAT, Y., ZAREI, M., & SAKINEZHAD, A.. (2012). SYNTHESIS OF 2, 4, 6, 8, 10, 12-HEXABENZYL-2, 4, 6, 8, 10, 12-HEXAAZATETRACYCLO [5, 5, 0, 03, 11, 05, 9] DODECANE VIA NEW CATALYSTS. JOURNAL OF ENERGETIC MATERIALS, 6(3 (13)), 3-7. SID. https://sid.ir/paper/115469/en

    Vancouver: Copy

    BAYAT Y., ZAREI M., SAKINEZHAD A.. SYNTHESIS OF 2, 4, 6, 8, 10, 12-HEXABENZYL-2, 4, 6, 8, 10, 12-HEXAAZATETRACYCLO [5, 5, 0, 03, 11, 05, 9] DODECANE VIA NEW CATALYSTS. JOURNAL OF ENERGETIC MATERIALS[Internet]. 2012;6(3 (13)):3-7. Available from: https://sid.ir/paper/115469/en

    IEEE: Copy

    Y. BAYAT, M. ZAREI, and A. SAKINEZHAD, “SYNTHESIS OF 2, 4, 6, 8, 10, 12-HEXABENZYL-2, 4, 6, 8, 10, 12-HEXAAZATETRACYCLO [5, 5, 0, 03, 11, 05, 9] DODECANE VIA NEW CATALYSTS,” JOURNAL OF ENERGETIC MATERIALS, vol. 6, no. 3 (13), pp. 3–7, 2012, [Online]. Available: https://sid.ir/paper/115469/en

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