COMPARISON OF SOME CARBON NANOSTRUCTURES CATALYTIC EFFECTS ON HYDROGEN DESORPTION IN SODIUM ALANATE AS A SOURCE OF HYDROGEN STORAGE IN FUEL CELLS

Q: How can I download an article?

To download an article from SID, first log in to the site, search for the article title, and click on the 'Download Article' option.

Q: How can I download an ISI article?

To download an ISI article on SID, enter the keyword or article title in the search bar, view the relevant results, click on the desired article, and select the 'Download Article' option.

Q: How can I access the SID database?

To access the SID database, visit SID.ir, create an account, and log in to access scientific resources.

Q: Is downloading articles from SID free?

Some articles on SID are available for free, while others require payment. Details are specified on the article's page.

RAFIEE M.

مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

Journal Paper

Paper Information

Journal: Journal of Applied Research in Chemistry Year:2017 | Volume:11 | Issue:3 Page(s): 51-56

Download Full-Text

Persian Verion

View:

641

Download:

Cites:

Information Journal Paper

Title

COMPARISON OF SOME CARBON NANOSTRUCTURES CATALYTIC EFFECTS ON HYDROGEN DESORPTION IN SODIUM ALANATE AS A SOURCE OF HYDROGEN STORAGE IN FUEL CELLS

Author(s)

RAFIEE M. | Issue Writer Certificate

Keywords

HYDROGEN STORAGEQ2

NUCLEAR QUADRUPOLE RESONANCE (NQR)Q1

NUCLEAR QUADRUPOLE COUPLING CONSTANT (NQCC)Q1

SODIUM ALANATEQ1

Abstract

Quadrupolar parameters of nuclei can be used as a tool to understand the electronic structure of the compounds. SODIUM ALANATE (NaAlH4) is a potential HYDROGEN STORAGE material due to its outstanding hydrogen capacity; however, its high thermodynamic stability is unfavorable for dehydrogenation processes. Carbon nanostructures as catalyst can reversibly store hydrogen. Understanding the bonding nature of Al and H is essential for improving its dehydrogenation performance. In this work, the charge density distribution of NaAlH4 was studied in the presence of some carbon nanostructures. For this purpose, using calculated NQCCs of hydrogen atoms, the electronic structure of pure NaAlH4 with NaAlH4 in the presence of some carbon nanostructures were compared. The results show that fullerene–NaAlH4 composite demonstrates better catalytic properties with very small 2H-NQCC. Therefore, hydrogens in the mentioned composite have weaker bond with Al. In other words, easier condition for dehydrogenation in fullerene–NaAlH4 is expected. The electric field gradient (EFG) at the site of quadrupolar nuclei was calculated to obtain NQCC parameters using Gaussian 03 at HF/6-31G* level of theory.

Cites

No record.

References

No record.

Cite

APA: Copy

RAFIEE, M.. (2017). COMPARISON OF SOME CARBON NANOSTRUCTURES CATALYTIC EFFECTS ON HYDROGEN DESORPTION IN SODIUM ALANATE AS A SOURCE OF HYDROGEN STORAGE IN FUEL CELLS. JOURNAL OF APPLIED RESEARCHES IN CHEMISTRY (JARC), 11(3 ), 51-56. SID. https://sid.ir/paper/179980/en

Vancouver: Copy

RAFIEE M.. COMPARISON OF SOME CARBON NANOSTRUCTURES CATALYTIC EFFECTS ON HYDROGEN DESORPTION IN SODIUM ALANATE AS A SOURCE OF HYDROGEN STORAGE IN FUEL CELLS. JOURNAL OF APPLIED RESEARCHES IN CHEMISTRY (JARC)[Internet]. 2017;11(3 ):51-56. Available from: https://sid.ir/paper/179980/en

IEEE: Copy

M. RAFIEE, “COMPARISON OF SOME CARBON NANOSTRUCTURES CATALYTIC EFFECTS ON HYDROGEN DESORPTION IN SODIUM ALANATE AS A SOURCE OF HYDROGEN STORAGE IN FUEL CELLS,” JOURNAL OF APPLIED RESEARCHES IN CHEMISTRY (JARC), vol. 11, no. 3 , pp. 51–56, 2017, [Online]. Available: https://sid.ir/paper/179980/en

Related Journal Papers