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Information Journal Paper

Title

EXTRACTION OF LANTHANIDES FROM AQUEOUS SOLUTIONS USING CYANEX 301 IMPREGNATED XAD-4 RESIN

Pages

  23-32

Abstract

 In the present study, the adsorption behavior of an impregnated resin (Ambrlite XAD-4 / CYANEX 301) in the presence of La (III), Sm (III), Ce (III), Gd (III), Dy (III), Nd (III) and Lu (III) ions were examined in aqueous media. In order to prepare impregnated resin, a desired amount of CYANEX 301 was diluted with ethanol at 1:1 volume ratio and then impregnation process was performed in a shaker with speed of 100 rpm at 25oC during 24 hours. After separating the resin from the solution by filter paper, it was placed in an oven at 40oC for 48 hours. The amount of impregnated CYANEX 301 was determined to be 49 percent. The kd values of metal ions were determined under various pH, nitric acid, temperature and different amount of the adsorbent. To determine the amounts of metal ions, an inductively coupled plasma (ICP-AES) was used. The results showed that the maximum uptake for some heavy lanthanides such as Dy (III) and Lu (III) were take placed at the pHs less than 4.8 while for La (III) and medium lanthanides, the maximum uptake values were observed in pH=5.1 and 4.3, respectively. Such behavior shows that it is possible to separate light lanthanides from heavy ones using the variation of pH. Based on these kd results, it can be concluded that the lanthanides uptake decrease with increasing acid concentration.

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    APA: Copy

    DELRISH, E., KHANCHI, A.R., & AHMADI, J.. (2014). EXTRACTION OF LANTHANIDES FROM AQUEOUS SOLUTIONS USING CYANEX 301 IMPREGNATED XAD-4 RESIN. JOURNAL OF APPLIED RESEARCHES IN CHEMISTRY (JARC), 8(3), 23-32. SID. https://sid.ir/paper/180045/en

    Vancouver: Copy

    DELRISH E., KHANCHI A.R., AHMADI J.. EXTRACTION OF LANTHANIDES FROM AQUEOUS SOLUTIONS USING CYANEX 301 IMPREGNATED XAD-4 RESIN. JOURNAL OF APPLIED RESEARCHES IN CHEMISTRY (JARC)[Internet]. 2014;8(3):23-32. Available from: https://sid.ir/paper/180045/en

    IEEE: Copy

    E. DELRISH, A.R. KHANCHI, and J. AHMADI, “EXTRACTION OF LANTHANIDES FROM AQUEOUS SOLUTIONS USING CYANEX 301 IMPREGNATED XAD-4 RESIN,” JOURNAL OF APPLIED RESEARCHES IN CHEMISTRY (JARC), vol. 8, no. 3, pp. 23–32, 2014, [Online]. Available: https://sid.ir/paper/180045/en

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