INFLUENCE OF CEO2 ON FUEL CELL GRADE HYDROGEN PRODUCTION FROM STEAM REFORMING OF METHANOL OVER NANOSTRUCTURED MIXED OXIDES OF CU, ZN AND AL SYNTHESIZED VIA UREA-NITRATE COMBUSTION METHOD

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MINAEI SH.; HAGHIGHI M.; JODEIRI N.; ABDOLLAHIFAR M.; AJAMEIN H.

مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

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Journal: Journal of Applied Research in Chemistry Year:2014 | Volume:8 | Issue:3 Page(s): 33-44

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Title

INFLUENCE OF CEO2 ON FUEL CELL GRADE HYDROGEN PRODUCTION FROM STEAM REFORMING OF METHANOL OVER NANOSTRUCTURED MIXED OXIDES OF CU, ZN AND AL SYNTHESIZED VIA UREA-NITRATE COMBUSTION METHOD

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Keywords

UREA-NITRATES COMBUSTIONQ2

CU/ZN/CE/AL OXIDESQ2

METHANOL REFORMINGQ2

HYDROGENQ2

Abstract

In this study, the effect of ceria as a promoter on the performance of synthesized nanostructured mixed oxides has been investigated in the steam METHANOL REFORMING process. Urea nitrate combustion method is recommended as a novel, rapid, and simple process to achieve nanoporous structure. Synthesized nanostructured mixed oxides, after shaping, were evaluated in catalytic performance study system at 200-300oC temperature range under atomospheric pressure. The phsycochemical properties of synthesized nanostructured mixed oxides were studied by XRD, FT-IR, FESEM, BET, and SEM-EDX analyses. CuO and ZnO were detected in XRD patterns and alumina presence was proved via SEM-EDX and FT-IR since no peaks could be detected in XRD patterns. FESEM images showed that particles of synthesized samples were in nano range. It was seen that relative christallinity decreased slightly. Catalytic performance study showed that ceria increased methanol conversion and HYDROGEN selectivity while decreased selectivity of CO and CO2 as undesired products.

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APA: Copy

MINAEI, SH., HAGHIGHI, M., JODEIRI, N., ABDOLLAHIFAR, M., & AJAMEIN, H.. (2014). INFLUENCE OF CEO₂ ON FUEL CELL GRADE HYDROGEN PRODUCTION FROM STEAM REFORMING OF METHANOL OVER NANOSTRUCTURED MIXED OXIDES OF CU, ZN AND AL SYNTHESIZED VIA UREA-NITRATE COMBUSTION METHOD. JOURNAL OF APPLIED RESEARCHES IN CHEMISTRY (JARC), 8(3), 33-44. SID. https://sid.ir/paper/180050/en

Vancouver: Copy

MINAEI SH., HAGHIGHI M., JODEIRI N., ABDOLLAHIFAR M., AJAMEIN H.. INFLUENCE OF CEO₂ ON FUEL CELL GRADE HYDROGEN PRODUCTION FROM STEAM REFORMING OF METHANOL OVER NANOSTRUCTURED MIXED OXIDES OF CU, ZN AND AL SYNTHESIZED VIA UREA-NITRATE COMBUSTION METHOD. JOURNAL OF APPLIED RESEARCHES IN CHEMISTRY (JARC)[Internet]. 2014;8(3):33-44. Available from: https://sid.ir/paper/180050/en

IEEE: Copy

SH. MINAEI, M. HAGHIGHI, N. JODEIRI, M. ABDOLLAHIFAR, and H. AJAMEIN, “INFLUENCE OF CEO₂ ON FUEL CELL GRADE HYDROGEN PRODUCTION FROM STEAM REFORMING OF METHANOL OVER NANOSTRUCTURED MIXED OXIDES OF CU, ZN AND AL SYNTHESIZED VIA UREA-NITRATE COMBUSTION METHOD,” JOURNAL OF APPLIED RESEARCHES IN CHEMISTRY (JARC), vol. 8, no. 3, pp. 33–44, 2014, [Online]. Available: https://sid.ir/paper/180050/en

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